Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
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Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene.[3,3]-Sigmatropic rearrangement step in the gold-catalyzed cyclization of allyl-(ortho-alkinylphenyl)methyl ethers.Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (L11(AuCl)), 933752 (L12(AuCl)a), 933753 (L9(AuCl)), 933754 (L10(AuCl)), 933756 (L8(AuCl)), 933757 (L12(ATotal Synthesis, Stereochemical Revision, and Biological Reassessment of Mandelalide A: Chemical Mimicry of Intrafamily Relationships.Reaction discovery employing macrocycles: transannular cyclizations of macrocyclic bis-lactamsGold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienesStoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp2)-H arylation.Synthesis and biological evaluation of ABCD ring fragments of the kibdelonesA cycloisomerization/Friedel-Crafts alkylation strategy for the synthesis of pyrano[3,4-b]indolesGold-catalyzed diastereoselective cycloisomerization of alkylidene-cyclopropane-bearing 1,6-diynesGold-catalyzed cyclizations of cis-enediynes: insights into the nature of gold-aryne interactions.Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclizationDinuclear gold-silver resting states may explain silver effects in gold(I)-catalysisElectrophilic Pt(II) complexes: precision instruments for the initiation of transformations mediated by the cation-olefin reaction.Gold(I)-catalyzed intramolecular hydroarylation of allenes.Gold for C-C coupling reactions: a Swiss-Army-knife catalyst?C-H bond functionalization via hydride transfer: direct coupling of unactivated alkynes and sp(3) C-H bonds catalyzed by platinum tetraiodide.Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.Studies toward the unique pederin family member psymberin: full structure elucidation, two alternative total syntheses, and analogsGold-catalyzed cycloisomerization of 1,5-allenynes via dual activation of an ene reaction.Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered RingsGold catalysis: catalyst oxidation state dependent dichotomy in the cyclization of furan-yne systems with aromatic tethers.Phosphoramidite gold(I)-catalyzed diastereo- and enantioselective synthesis of 3,4-substituted pyrrolidinesDriving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride AbstractorsAtom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: substrate scope and experimental and theoretical mechanistic investigation.On the validity of Au-vinylidenes in the gold-catalyzed 1,2-migratory cycloisomerization of skipped propargylpyridines.Recent advances in the gold-catalyzed additions to C-C multiple bonds.A racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-1,6-enynes as the key strategy.Synthetic applications of gold-catalyzed ring expansions.Combinatorial approach to chiral tris-ligated carbophilic platinum complexes: application to asymmetric catalysis.Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt(2+) CatalystsDirect access to pyrido/pyrrolo[2,1-b]quinazolin-9(1H)-ones through silver-mediated intramolecular alkyne hydroamination reactions.Experimental and computational evidence for gold vinylidenes: generation from terminal alkynes via a bifurcation pathway and facile C-H insertionsMechanism of gold(I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment.Chiral cyclopentadienyl iridium(III) complexes promote enantioselective cycloisomerizations giving fused cyclopropanes.Gold(I)-catalysed direct thioetherifications using allylic alcohols: an experimental and computational study.Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study.Terminating platinum-initiated cation-olefin reactions with simple alkenes.Catalytic coupling of arene C-H bonds and alkynes for the synthesis of coumarins: substrate scope and application to the development of neuroimaging agents.
P2860
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P2860
Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
@en
type
label
Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
@en
prefLabel
Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
@en
P356
P1476
Catalytic carbophilic activation: catalysis by platinum and gold pi acids.
@en
P304
P356
10.1002/ANIE.200604335
P407
P577
2007-01-01T00:00:00Z