Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
about
Steric control of alpha- and beta-alkylation of azulenone intermediates in a guanacastepene a synthesisRhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation.The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization.Scope and Mechanistic Study of the Coupling Reaction of α, β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling PathwaysRhodium catalyzed chelation-assisted C-H bond functionalization reactionsRh(I)-Catalyzed Cycloisomerization of 1,6-EnynesTetrasubstituted olefins through the stereoselective catalytic intermolecular conjugate addition of simple alkenes to α,β-unsaturated carbonyl compounds.Catalytic methodologies for the β-boration of conjugated electron deficient alkenes.C-H activation: a complementary tool in the total synthesis of complex natural products.Diastereoselective carbocyclization of 1,6-heptadienes triggered by rhodium-catalyzed activation of an olefinic C-H bond.Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines.Cobalt-catalyzed, aminoquinoline-directed coupling of sp(2) C-H bonds with alkenesAsymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation.Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C-H Functionalization Sequences.Preparative Synthesis of Highly Substituted Tetrahydropyridines via a Rh(I)-Catalyzed C-H Functionalization Sequence.Cross-coupling/annulations of quinazolones with alkynes for access to fused polycyclic heteroarenes under mild conditions.Acid-catalyzed direct conjugate alkenylation of α,β-unsaturated ketones.Rhodium(III)-catalyzed vinylic sp2 C-H bond functionalization: efficient synthesis of pyrido[1,2-α]benzimidazoles and imidazo[1,2-α]pyridines.Cyclopentanone Derivatives from 5-Hydroxymethylfurfural via 1-Hydroxyhexane-2,5-dione as Intermediate.Enantioselective Formal C-H Conjugate Addition of Acetanilides to β-Substituted Acrylates by Chiral Iridium Catalysts.Aminoquinoline-assisted vinylic C-H arylation of unsubstituted acrylamide for the selective synthesis of Z olefins.Taming living carbocations in catalytic direct conjugate addition of simple alkenes to α,β-enones.Undirected Arene and Chelate-Assisted Olefin C-H Bond Activation: [RhIIICp*]-Catalyzed Dehydrogenative Alkene-Arene Coupling as a New Pathway for the Selective Synthesis of Highly SubstitutedZOlefins
P2860
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P2860
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
2006年论文
@zh
2006年论文
@zh-cn
name
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
@en
type
label
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
@en
prefLabel
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
@en
P2093
P2860
P356
P1476
Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation
@en
P2093
Denise A Colby
Jonathan A Ellman
Robert G Bergman
P2860
P304
P356
10.1021/JA0584931
P407
P577
2006-05-01T00:00:00Z