Oxidative palladium(II) catalysis: A highly efficient and chemoselective cross-coupling method for carbon-carbon bond formation under base-free and nitrogenous-ligand conditions
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Expeditious Enyne Construction from Alkynes via Oxidative Pd(II) Catalyzed Heck-Type Coupling.Enantioselective construction of remote quaternary stereocentresAsymmetric intermolecular boron Heck-type reactions via oxidative palladium(II) catalysis with chiral tridentate NHC-amidate-alkoxide ligandsPalladium-catalyzed oxidative intermolecular difunctionalization of terminal alkenes with organostannanes and molecular oxygenPd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins.Allylic substitution versus Suzuki cross-coupling: capitalizing on chemoselectivity with bifunctional substratesTransmetallation versus β-hydride elimination: the role of 1,4-benzoquinone in chelation-controlled arylation reactions with arylboronic acids.A highly selective and general palladium catalyst for the oxidative Heck reaction of electronically nonbiased olefins.Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically nonbiased olefins.Oxidative Heck Reactions using Aryltrifluoroborates and Aryl N-Methyliminodiacetic Acid (MIDA) BoronatesDevelopment and Investigation of a Site Selective Palladium-Catalyzed 1,4-Difunctionalization of Isoprene using Pyridine-Oxazoline Ligands.Expanded substrate scope and improved reactivity of ether-forming cross-coupling reactions of organotrifluoroborates and acetals.Catalytic Properties of Unsupported Palladium Nanoparticle Surfaces Capped with Small Organic LigandsCatalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions.Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.Chemoselective Three-Component Coupling via A Tandem Pd Catalyzed Boron-Heck and Suzuki Reaction.Palladium-Catalyzed 1,3-Difunctionalization Using Terminal Alkenes with Alkenyl Nonaflates and Aryl Boronic AcidsBoron-Heck reaction of cyclic enaminones: regioselective direct arylation via oxidative palladium(II) catalysis.Enantioselective oxidative boron Heck reactions.Synthesis of functionalized cinnamaldehyde derivatives by an oxidative Heck reaction and their use as starting materials for preparation of Mycobacterium tuberculosis 1-deoxy-D-xylulose-5-phosphate reductoisomerase inhibitors.Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant.Iterative Cross-Couplng with MIDA Boronates: Towards a General Platform for Small Molecule Synthesis.Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes.Aqueous oxidative Heck reaction as a protein-labeling strategy.Oxidative Heck vinylation for the synthesis of complex dienes and polyenes.Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.Pd(II)-catalyzed highly selective arylation of allyl esters via C-H functionalization of unreactive arenes with retention of the traditional leaving group.Synthesis of conjugated dienes via a biomimetic aerobic oxidative coupling of two C(vinyl)-H bonds.Scalable synthesis of oxazolones from propargylic alcohols through multistep palladium(II) catalysis: β-selective oxidative Heck coupling of cyclic sulfonyl enamides and aryl boroxines.Cobalt-Catalyzed Alkenylzincation of Unfunctionalized Alkynes.Auto-Tandem Catalysis: PdII -Catalysed Dehydrogenation/Oxidative Heck Reaction of Cyclopentane-1,3-diones.Oxidative Mizoroki-Heck-type reaction of arylsulfonyl hydrazides for a highly regio- and stereoselective synthesis of polysubstituted alkenes.Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: application to the synthesis of the C13-C21 fragment of palmerolide A.Stereoselective synthesis of highly substituted enamides by an oxidative Heck reaction.Palladium-catalyzed aerobic oxidative cross-coupling of arylhydrazines with terminal alkynes.Ligand-free palladium-catalyzed aerobic oxidative coupling of carboxylic anhydrides with arylboronic acids.A versatile approach to flavones via a one-pot Pd(II)-catalyzed dehydrogenation/oxidative boron-Heck coupling sequence of chromanones.Characterization and photocatalytic behavior of 2,9-di(aryl)-1,10-phenanthroline copper(i) complexes.Synthesis of unsymmetrical biaryl ethers through nickel-promoted coupling of polyfluoroarenes with arylboronic acids and oxygen.
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P2860
Oxidative palladium(II) catalysis: A highly efficient and chemoselective cross-coupling method for carbon-carbon bond formation under base-free and nitrogenous-ligand conditions
description
article científic
@ca
article scientifique
@fr
articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on December 2006
@en
vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Oxidative palladium
@nl
Oxidative palladium(II) cataly ...... nitrogenous-ligand conditions
@en
type
label
Oxidative palladium
@nl
Oxidative palladium(II) cataly ...... nitrogenous-ligand conditions
@en
prefLabel
Oxidative palladium
@nl
Oxidative palladium(II) cataly ...... nitrogenous-ligand conditions
@en
P2093
P2860
P356
P1476
Oxidative palladium(II) cataly ...... nitrogenous-ligand conditions
@en
P2093
Cheol Hwan Yoon
Kyung Soo Yoo
Kyung Woon Jung
Rajesh K Mishra
Sung Wook Yi
Young Chun Jung
P2860
P304
16384-16393
P356
10.1021/JA063710Z
P407
P577
2006-12-01T00:00:00Z