Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents.
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Glymes as Versatile Solvents for Chemical Reactions and Processes: from the Laboratory to Industry.Enantioselective alkenylation via nickel-catalyzed cross-coupling with organozirconium reagentsStereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl AcetatesNickel/bis(oxazoline)-catalyzed asymmetric Kumada reactions of alkyl electrophiles: cross-couplings of racemic alpha-bromoketonesAsymmetric Suzuki cross-couplings of activated secondary alkyl electrophiles: arylations of racemic alpha-chloroamidesAsymmetric alkyl-alkyl cross-couplings of unactivated secondary alkyl electrophiles: stereoconvergent Suzuki reactions of racemic acylated halohydrinsStereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfonesCatalytic asymmetric synthesis of secondary nitriles via stereoconvergent Negishi arylations and alkenylations of racemic α-bromonitriles.Nickel-catalyzed Negishi arylations of propargylic bromides: a mechanistic investigationNICKEL-CATALYZED ENANTIOSELECTIVE NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY α-BROMO AMIDES WITH ALKYLZINC REAGENTS: (S)-N-BENZYL-7-CYANO-2-ETHYL-N-PHENYLHEPTANAMIDE.SYNTHESIS OF CHIRAL PYRIDINE BIS(OXAZOLINE) LIGANDS FOR NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: 2,6-BIS[(4S)-4,5-DIHYDRO-4-(2-PHENYLETHYL)-2-OXAZOLYL]-PYRIDINE.Nickel-catalyzed enantioselective cross-couplings of racemic secondary electrophiles that bear an oxygen leaving group.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsCatalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.Nonracemic Antifolates Stereoselectively Recruit Alternate Cofactors and Overcome Resistance in S. aureus.Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights.Nickel/bis(oxazoline)-catalyzed asymmetric Negishi arylations of racemic secondary benzylic electrophiles to generate enantioenriched 1,1-diarylalkanes.Catalytic asymmetric cross-couplings of racemic alpha-bromoketones with arylzinc reagents.Strategies and tactics for the metal-directed synthesis of rotaxanes, knots, catenanes, and higher order links.Insights into the elementary steps in Negishi coupling through kinetic investigations.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Organozinc Chemistry Enabled by Micellar Catalysis. Palladium-Catalyzed Cross-Couplings between Alkyl and Aryl Bromides in Water at Room Temperature.Re-Orienting Coupling of Organocuprates with Propargyl Electrophiles from SN2' to SN2 with Stereocontrol.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates.N-Heterocyclic Carbene Bound Nickel(I) Complexes and Their Roles in Catalysis.Functional-group-tolerant, nickel-catalyzed cross-coupling reaction for enantioselective construction of tertiary methyl-bearing stereocenters.Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters.Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents.NiI Catalyzes the Regioselective Cross-Coupling of Alkylzinc Halides and Propargyl Bromides to Allenes.Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs.Nickel(II)-catalyzed diastereoselective [3+2] cycloaddition of N-tosyl-aziridines and aldehydes via selective carbon-carbon bond cleavage.Lewis acid-catalyzed formal [3+2] cycloadditions of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage.Ethylaluminum as an ethylene source for the Mizoroki-Heck-type reaction. Rhodium-catalyzed preparation of stilbene derivatives.Direct Substitution of Arylalkynyl Carbinols Provides Access to Diverse Terminal Acetylene Building Blocks.
P2860
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P2860
Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 03 September 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@en
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
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type
label
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@en
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@nl
prefLabel
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@en
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@nl
P2860
P356
P1476
Nickel-catalyzed asymmetric cr ...... alides with arylzinc reagents.
@en
P2093
Gregory C Fu
Sean W Smith
P2860
P304
12645-12647
P356
10.1021/JA805165Y
P407
P577
2008-09-03T00:00:00Z