Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
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Contemporary Strategies for the Synthesis of Tetrahydropyran Derivatives: Application to Total Synthesis of Neopeltolide, a Marine Macrolide Natural ProductOlefin metathesis in airSynthesis and crossover reaction of TEMPO containing block copolymer via ROMP.Chiral-at-metal complexes and their catalytic applications in organic synthesis.Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido LigandEndo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes.Synthesis of (±)-tetrapetalone A-Me aglycon.Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by MonoAryloxidePyrrolide (MAP) CatalystsCatalytic Z-selective olefin cross-metathesis for natural product synthesis.Highly selective ruthenium metathesis catalysts for ethenolysis.Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten CatalystsIsolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures.Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesisZ-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexesBipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes.Catalytic enantioselective synthesis of quaternary carbon stereocentresCatalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and moreInversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum.Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex.Recent advances in high oxidation state Mo and W imido alkylidene chemistry.Highly Z-selective metathesis homocoupling of terminal olefins.Asymmetric catalysts for stereocontrolled olefin metathesis reactions.Dynamic asymmetric organocatalysis: cooperative effects of weak interactions and conformational flexibility in asymmetric organocatalysts.A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, amEndo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Tandem Olefin Metathesis/Oxidative Cyclization: Synthesis of Tetrahydrofuran Diols from Simple Olefins.Light-induced olefin metathesis.Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis.Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide.Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols.The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes.A concise and versatile double-cyclization strategy for the highly stereoselective synthesis and arylative dimerization of Aspidosperma alkaloids.Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesisEnantioselective olefin metathesis with cyclometalated ruthenium complexes.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes.Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile.
P2860
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P2860
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
@en
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis.
@nl
type
label
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
@en
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis.
@nl
prefLabel
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
@en
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis.
@nl
P2093
P2860
P356
P1433
P1476
Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis
@en
P2093
Elizabeth S Sattely
Simon J Meek
Steven J Malcolmson
P2860
P2888
P304
P356
10.1038/NATURE07594
P407
P577
2008-11-16T00:00:00Z
P5875
P6179
1044186419