Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
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Merging rhodium-catalysed C-H activation and hydroamination in a highly selective [4+2] imine/alkyne annulationRegio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers.Stereocontrolled synthesis of vicinally functionalized piperidines by nucleophilic β-addition of alkyllithiums to α-aryl substituted piperidine enecarbamates.Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from TetrahydropyridinesCatalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights.Rh(I)-Catalyzed Cycloisomerization of 1,6-EnynesSynthesis of ent-ketorfanol via a C-H alkenylation/torquoselective 6π electrocyclization cascade.Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systemsExpedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation.Chemical structure, biosynthesis and synthesis of free and glycosylated pyridinolines formed by cross-link of bone and synovium collagen.Synthesis and Utility of Dihydropyridine Boronic Esters.Associative Covalent Relay: An Oxadiazolone Strategy for Rhodium(III)-Catalyzed Synthesis of Primary Pyridinylamines.Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds.A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether.Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C-H Functionalization Sequences.Preparative Synthesis of Highly Substituted Tetrahydropyridines via a Rh(I)-Catalyzed C-H Functionalization Sequence.Directed functionalization of 1,2-dihydropyridines: stereoselective synthesis of 2,6-disubstituted piperidines.
P2860
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P2860
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on February 2013
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@en
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@nl
type
label
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@en
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@nl
prefLabel
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@en
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@nl
P2093
P2860
P356
P1433
P1476
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
@en
P2093
Jonathan A Ellman
Kenneth B Wiberg
Michael K Takase
Robert G Bergman
Shuming Chen
P2860
P304
P356
10.1126/SCIENCE.1230704
P407
P577
2013-02-01T00:00:00Z