Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes.
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Vinylogous reactivity of enol diazoacetates with donor-acceptor substituted hydrazones. Synthesis of substituted pyrazole derivatives.Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone.Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates.The [3 + 3]-cycloaddition alternative for heterocycle syntheses: catalytically generated metalloenolcarbenes as dipolar adducts.Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process.α-Diazo oxime ethers for N-heterocycle synthesis.Gold-catalyzed α-furanylations of quinoline N-oxides with alkenyldiazo carbonyl species.Reaction of alkynes and azides: not triazoles through copper-acetylides but oxazoles through copper-nitrene intermediates.The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes.Palladium-catalyzed imidoylative cyclization of α-isocyanoacetamides: efficient access to C2-diversified oxazoles.Expedient access to substituted 3-amino-2-cyclopentenones by dirhodium-catalyzed [3+2]-annulation of silylated ketene imines and enoldiazoacetates.Copper-catalyzed annulation of α-substituted diazoacetates with 2-ethynylanilines: the direct synthesis of C2-functionalized indoles.
P2860
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P2860
Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on December 2012
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Efficient synthesis of oxazoles by dirhodium
@nl
Efficient synthesis of oxazole ...... yryl diazoacetate with oximes.
@en
type
label
Efficient synthesis of oxazoles by dirhodium
@nl
Efficient synthesis of oxazole ...... yryl diazoacetate with oximes.
@en
prefLabel
Efficient synthesis of oxazoles by dirhodium
@nl
Efficient synthesis of oxazole ...... yryl diazoacetate with oximes.
@en
P2860
P50
P356
P1476
Efficient synthesis of oxazole ...... tyryl diazoacetate with oximes
@en
P2093
Michael P Doyle
P2860
P304
11522-11524
P356
10.1039/C2CC36537E
P407
P577
2012-12-01T00:00:00Z