Selective synthesis of 5- or 6-aryl octahydrocyclopenta[b]pyrroles from a common precursor through control of competing pathways in a Pd-catalyzed reaction.
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Biaryl Phosphane Ligands in Palladium-Catalyzed AminationSynthesis of N-Aryl-2-allyl Pyrrolidines via Palladium-catalyzed Carboamination Reactions of γ-(N-Arylamino)alkenes with Vinyl Bromides.Pd(OAc)(2)-catalyzed domino reactions of 1,2-dihaloarenes and 2-haloaryl arenesulfonates with Grignard reagents: efficient synthesis of substituted fluorenes.Intramolecular aminopalladation of alkenes as a key step to pyrrolidines and related heterocycles.Recent developments of ketene dithioacetal chemistry.A conceptual framework for analysing and planning synthetic approaches to diverse lead-like scaffolds.Reaching the south: metal-catalyzed transformation of the aromatic para-position.Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions.Use of aryl chlorides as electrophiles in Pd-catalyzed alkene difunctionalization reactions.Pd-catalyzed carboamination of oxazolidin-2-ones: a stereoselective route to trans-2,5-disubstituted pyrrolidines.Palladium-Catalyzed Carboetherification and Carboamination Reactions of γ-Hydroxy- and γ-Aminoalkenes for the Synthesis of Tetrahydrofurans and Pyrrolidines.Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer.Stereoselective synthesis of imidazolidin-2-ones via Pd-catalyzed alkene carboamination. Scope and limitations.Palladium-catalyzed synthesis of 2,1'-disubstituted tetrahydrofurans from gamma-hydroxy internal alkenes. Evidence for alkene insertion into a Pd-O bond and stereochemical scrambling via beta-hydride elimination.Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer.A new synthesis of imidazolidin-2-ones via Pd-catalyzed carboamination of N-allylureas.Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactionsPalladium-catalyzed alkene carboamination reactions for the synthesis of substituted piperazines.Mild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation.Asymmetric palladium-catalyzed carboamination reactions for the synthesis of enantiomerically enriched 2-(arylmethyl)- and 2-(alkenylmethyl)pyrrolidines.Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladationMild conditions for the synthesis of functionalized pyrrolidines via Pd-catalyzed carboamination reactions.Two palladium-catalyzed domino reactions from one set of substrates/reagents: efficient synthesis of substituted indenes and cis-stilbenoid hydrocarbons from the same internal alkynes and hindered Grignard reagents.Synthesis of saturated 1,4-benzodiazepines via Pd-catalyzed carboamination reactions.Palladium-catalyzed synthesis of cyclopentane-fused benzocyclobutenes via tandem directed carbopalladation/C-H bond functionalization.A concise stereoselective synthesis of Preussin, 3-epi-Preussin, and analogues.Intramolecular Pd-catalyzed carboetherification and carboamination. Influence of catalyst structure on reaction mechanism and product stereochemistry.Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine.A concise asymmetric synthesis of cis-2,6-disubstituted N-aryl piperazines via Pd-catalyzed carboamination reactions.Oxidative addition to palladium(0) diphosphine complexes: observations of mechanistic complexity with iodobenzene as reactant.Palladium-Catalyzed Ring-Forming Aminoalkenylation of Alkenes with Aldehydes Initiated by Intramolecular Aminopalladation.Expedient and modular access to 2-azabicyclic architectures by iron-catalyzed dehydrative coupling of alcohol-bearing allylic lactams.Regiodivergent heterocyclization: a strategy for the synthesis of substituted pyrroles and furans using α-formyl ketene dithioacetals as common precursors.
P2860
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P2860
Selective synthesis of 5- or 6-aryl octahydrocyclopenta[b]pyrroles from a common precursor through control of competing pathways in a Pd-catalyzed reaction.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on June 2005
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@en
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@nl
type
label
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@en
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@nl
prefLabel
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@en
Selective synthesis of 5- or 6 ...... ys in a Pd-catalyzed reaction.
@nl
P2860
P356
P1476
Selective synthesis of 5- or 6 ...... ays in a Pd-catalyzed reaction
@en
P2093
Joshua E Ney
P2860
P304
P356
10.1021/JA0430346
P407
P577
2005-06-01T00:00:00Z