Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
about
Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective HydrocuprationMetal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition.Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates.Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates.Broad-spectrum kinetic resolution of alcohols enabled by Cu-H-catalysed dehydrogenative coupling with hydrosilanes.CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines.Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes.Enantioselective Copper-Catalyzed Alkylation of Quinoline N-Oxides with Vinylarenes.Cobalt-Based Active Species Molecularly Immobilized on Carbon Nanotubes for the Oxygen Reduction Reaction.Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design.Balancing C=C Functionalization and C=O Reduction in Cu-H Catalysis.A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes.2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.Versatile Homoallylic Boronates by Chemo-, SN 2'-, Diastereo- and Enantioselective Catalytic Sequence of Cu-H Addition to Vinyl-B(pin)/Allylic Substitution.Copper-Catalyzed Alkynylboration of Alkenes with Diboron Reagents and Bromoalkynes.Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates.Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds.Engaging dual donor sites within an N-heterocyclic olefin phosphine ligand.Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and their in situ addition to carbonyl compounds† †Electronic supplementary information (ESI) available. CCDC 1579294 and 1579300. For ESI and crystallographic data in CIFEnantio- and Diastereoselective Synthesis of Hydroxy Bis(boronates) via Cu-Catalyzed Tandem Borylation/1,2-Addition.Copper-Catalyzed Enantioselective Hydroamination of AlkenesAusbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
P2860
Q37229473-4056F80A-18AF-4ED1-869E-A619D3BEE97DQ39009434-28BB0B91-3751-4AF4-B8B0-DCC678AF489DQ41634333-1C6D3C95-F7C2-4C4B-87BD-9750803DD51BQ41671020-5334C427-1535-47FF-A7E5-A76CB396A382Q41890162-1CE55E7A-28C4-4826-9CE3-71869BF88819Q42631501-B2E28942-9C12-4181-9B3E-836079C97653Q42944775-35E343A4-775D-4EA6-A2B8-BAF9719384BEQ46281597-5E4AE6E7-F3C6-43EE-8FE9-F8549F0DC18BQ46348233-8E9B8437-7BAC-4411-BCBA-EBB14EC3073CQ48102918-620082FC-ED12-45A1-835B-254ABF801AABQ48127732-06BEEE97-C436-4D72-A760-C2DC46B1AEC8Q48153508-C062F999-7515-48C6-BEB4-BA63FF6E54B0Q48201372-D659E4C6-5F32-4FB7-9799-A08B42BCE5DCQ48355801-8FCA5F0A-4469-43BB-80E3-D397B08A8431Q49369452-E73D19C9-43D4-4ED1-B5F3-1055E1C2C871Q49829633-AF714BA3-AB01-4042-A2F5-C040B2DE402EQ50124413-3C99200C-457A-4E29-998B-BB1BFAA02308Q50205266-F200975E-057E-47ED-AE0A-8DF0604AC38EQ50656686-E786503C-4179-4702-8B50-21EF4DA23725Q55143224-22ED786F-90CB-4F47-8DE0-C6C94AA2B54AQ55266125-79D677AC-1948-4141-AE99-47C1C3792104Q55396228-F27B4EC5-97F3-4615-8BBB-4F8B4D47E944Q57150246-CF370EB4-B322-4C44-91FB-48377F9E81F2Q59203326-514EC9B5-69F7-4318-AAEF-8D541735F173
P2860
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 09 June 2016
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@en
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@nl
type
label
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@en
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@nl
prefLabel
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@en
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@nl
P2093
P2860
P356
P1433
P1476
Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.
@en
P2093
Stephen L Buchwald
P2860
P304
P356
10.1126/SCIENCE.AAF7720
P407
P577
2016-06-09T00:00:00Z