Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling.
about
Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" wayHighly selective synthesis of conjugated dienoic and trienoic esters via alkyne elementometalation-Pd-catalyzed cross-couplingHighly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of AlkenylboranesLigand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halidesArylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of ≥98% IsomericPurity. New Horizon in the Highly Selective Synthesis of Trisubstituted AlkenesHighly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol.Highly stereoselective total synthesis of fully hydroxy-protected mycolactones A and B and their stereoisomerization upon deprotectionCalyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C.Palladium-catalyzed completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophilesBorostannylation of alkynes and enynes. Scope and limitations of the reaction and utility of the adducts.Haloboration of internal alkynes with boronium and borenium cations as a route to tetrasubstituted alkenes.Synthesis of (Z)-N-alkenylazoles and pyrroloisoquinolines from α-N-azoleketones through Pd-catalyzed tosylhydrazone cross-couplings.Metal-Free Direct Alkylation of Ketene Dithioacetals by Oxidative C(sp2 )-H/C(sp3 )-H Cross-Coupling.The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies.Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis.One-step synthesis of conjugated enynenitriles from bromocyanoacetylene.A regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes.Stereo- and Regiocontrolled Methylboration of Terminal Alkynes.Synthesis of Alkenylboronic Esters: An Alternative Route to Trisubstituted Homoallylic Alcohols
P2860
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P2860
Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on September 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Highly regio- and stereoselect ...... m Pd-catalyzed cross-coupling.
@en
Highly regio- and stereoselective synthesis of
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type
label
Highly regio- and stereoselect ...... m Pd-catalyzed cross-coupling.
@en
Highly regio- and stereoselective synthesis of
@nl
prefLabel
Highly regio- and stereoselect ...... m Pd-catalyzed cross-coupling.
@en
Highly regio- and stereoselective synthesis of
@nl
P2093
P2860
P356
P1433
P1476
Highly regio- and stereoselect ...... m Pd-catalyzed cross-coupling.
@en
P2093
Ei-ichi Negishi
Tomas Tobrman
Zhaoqing Xu
P2860
P304
P356
10.1021/OL901566E
P407
P577
2009-09-01T00:00:00Z