Recent advances in enantioselective copper-catalyzed 1,4-addition.
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Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.α-Hydroxy ketones as useful templates in asymmetric reactions.Recent developments of ketene dithioacetal chemistry.Asymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.Advances in tandem reactions with organozinc reagents.Diastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesEnantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.Lewis Acid Enabled Copper-Catalyzed Asymmetric Synthesis of Chiral β-Substituted Amides.Chemoselectivity as a delineator of cuprate structure in catalytic 1,4-addition of diorganozinc reagents to Michael acceptors.Acid-catalyzed direct conjugate alkenylation of α,β-unsaturated ketones.Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.Chiral amides via copper-catalysed enantioselective conjugate addition.Hydrometallation-asymmetric conjugate addition: application to complex molecule synthesis.Efficient formation of benzylic quaternary centers via palladium catalysis.Palladium(0)/NHC-Catalyzed Reductive Heck Reaction of Enones: A Detailed Mechanistic Study.1,6-Conjugate addition of zinc alkyls to para-quinone methides in a continuous-flow microreactor.Asymmetric Sequential Cu-Catalyzed 1,6/1,4-Conjugate Additions of Hard Nucleophiles to Cyclic Dienones: Determination of Absolute Configurations and Origins of Enantioselectivity.A highly efficient Friedel-Crafts reaction of 3-hydroxyoxindoles and aromatic compounds to 3,3-diaryl and 3-alkyl-3-aryloxindoles catalyzed by Hg(ClO4)2·3H2O.Catalytic asymmetric addition of Grignard reagents to alkenyl-substituted aromatic N-heterocycles.Asymmetric conjugate addition of Grignard reagents to 3-silyl unsaturated esters for the facile preparation of enantioenriched β-silylcarbonyl compounds and allylic silanes.Reductive umpolung reactions with low-valent titanium catalysts.Catalytic enantioselective β-alkylation of α,β-unsaturated aldehydes by combination of transition-metal- and aminocatalysis: total synthesis of bisabolane sesquiterpenes.Formation of quaternary centres by copper catalysed asymmetric conjugate addition to β-substituted cyclopentenones with the aid of a quantitative structure-selectivity relationship.A convergent total synthesis of the telomerase inhibitor (±)-γ-rubromycin.Improved synthesis of cyclic tertiary allylic alcohols by asymmetric 1,2-addition of AlMe3 to enones.Enantioselective Intramolecular Reductive Heck Reaction with a Palladium/Monodentate Phosphoramidite CatalystCinchona alkaloid-based phosphoramide catalyzed highly enantioselective Michael addition of unprotected 3-substituted oxindoles to nitroolefinsA short synthesis of (±)-antroquinonol in an unusual scaffold of 4-hydroxy-2-cyclohexenone
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Recent advances in enantioselective copper-catalyzed 1,4-addition.
description
article científic
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article scientifique
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articolo scientifico
@it
artigo científico
@pt
bilimsel makale
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scientific article published on 11 February 2009
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vedecký článok
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vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@en
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@nl
type
label
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@en
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@nl
prefLabel
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@en
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@nl
P356
P1476
Recent advances in enantioselective copper-catalyzed 1,4-addition.
@en
P2093
M Gabriella Pizzuti
Thomas Jerphagnon
P304
P356
10.1039/B816853A
P577
2009-02-11T00:00:00Z