tert-Butanesulfinimines: structure, synthesis and synthetic applications.
about
The tert-butylsulfinamide lynchpin in transition-metal-mediated multiscaffold library synthesis.Solid-phase synthesis and chemical space analysis of a 190-membered alkaloid/terpenoid-like libraryAsymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization.Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids.Synthesis of fluorinated chiral amines using N-tert-butylsulfinyl imines.SYNTHESIS OF DE NOVO CHIRAL γ-AMINO-YNAMIDES USING LITHIATED YNAMIDES. OBSERVATION OF A UNIQUE 5-ENDO-DIG CYCLIZATION WITH AN INVERSION OF S-CENTER.Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones.A highly stereoselective addition of lithiated ynamides to Ellman-Davis chiral N-tert-butanesulfinyl imines.Synthesis of cis-C-iodo-N-tosyl-aziridines using diiodomethyllithium: reaction optimization, product scope and stability, and a protocol for selection of stationary phase for chromatography.Asymmetric catalytic N-phosphonyl imine chemistry: the use of primary free amino acids and Et2AlCN for asymmetric catalytic Strecker reaction.(S,2S,3R)-2-(2-Methyl-propane-2-sulfin-amido)-3-phenyl-butyronitrile.(S,2S,3S)-2-(2-Methyl-propan-2-sulfin-amido)-3-phenyl-butyronitrile.Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C-H Bond Addition CascadeAsymmetric synthesis of amines using tert-butanesulfinamide.Ru-Catalyzed highly diastereoselective hydrogenation of N-tert-butylsulfinyl ketimines for the synthesis of aryl glycine derivatives.An efficient approach to trans-4-hydroxy-5-substituted 2-pyrrolidinones through a stereoselective tandem Barbier process: divergent syntheses of (3R,4S)-statines, (+)-preussin and (-)-hapalosin.Synthesis and applications of masked oxo-sulfinamides in asymmetric synthesis.Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions.Asymmetric synthesis of chloroisothreonine derivatives via syn-stereoselective Mannich-type additions across N-sulfinyl-α-chloroimines.Convergent Synthesis of α-Branched Amines by Transition-Metal-Catalyzed C-H Bond Additions to Imines.Highly Selective Addition of a Broad Spectrum of Trimethylsilane Pro-nucleophiles to N-tert-Butanesulfinyl Imines.Design, synthesis, and application of a chiral sulfinamide phosphine catalyst for the enantioselective intramolecular rauhut-currier reaction.Chiral sulfoxide-olefin ligands: completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions.Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C-N bond cleavage.A practical entry to β-aryl-β-alkyl amino alcohols: application to the synthesis of a potent BACE1 inhibitor.Asymmetric Mannich reaction between (S)-N-(tert-butanesulfinyl)-3,3,3-trifluoroacetaldimine and malonic acid derivatives. Stereodivergent synthesis of (R)- and (S)-3-amino-4,4,4-trifluorobutanoic acids.Carbon-to-Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species
P2860
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P2860
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 26 January 2009
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vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
@cs
name
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@en
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@nl
type
label
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@en
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@nl
prefLabel
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@en
tert-Butanesulfinimines: structure, synthesis and synthetic applications.
@nl
P50
P356
P1476
tert-Butanesulfinimines: structure, synthesis and synthetic applications
@en
P2093
Fabrice Chemla
P304
P356
10.1039/B809772K
P577
2009-01-26T00:00:00Z