Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films.
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Oxidatively stable, aqueous europium(II) complexes through steric and electronic manipulation of cryptand coordination chemistry.Formation and structure of the first metal complexes comprising amidino-guanidinate ligands.Crystal structures of two ytterbium(III) complexes comprising alkynylamidinate ligands.Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story.Guanidines: from classical approaches to efficient catalytic syntheses.Recent development of synthetic preparation methods for guanidines via transition metal catalysis.Tris(N,N'-diisopropyl-benzamidinato)cerium(III).[N,N'-Bis(2,6-diisopropyl-phen-yl)methanimidamidato][η-1,4-bis-(tri-methyl-sil-yl)cyclo-octa-tetra-enyl](tetra-hydro-furan)-samarium(III) toluene monosolvate.Crystal and mol-ecular structures of two silver(I) amidinates, including an unexpected co-crystal with a lithium amidinate.A phosphorus-based compartmental ligand, (S)P[N(Me)N=CH-C6H3-2-O-3-OMe]3 (LH3), enables the assembly of luminescent heterobimetallic linear {L2Zn2Ln}+ [Ln = Gd, Tb, Nd and Eu] complexes.Synthesis, structures and reactivity of lanthanoid(II) formamidinates of varying steric bulk.Unprecedented reaction of bridged bis(guanidinate) lanthanide complexes: sterically induced deprotonation.Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the living polymerization of L-lactide and rac-lactide.Rare-earth dichloro and bis(alkyl) complexes supported by bulky amido-imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization.Divalent europium and ytterbium complexes supported by a bulky 2-pyridyl amido ligand: synthesis, structure and reactivity studies.Room temperature C-N bond cleavage of anionic guanidinate ligand in rare-earth metal complexes.An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction.Cationic Bismuth Amides: Accessibility, Structure, and Reactivity.Five different types of η(8)-cyclooctatetraenyl-lanthanide half-sandwich complexes from one ligand set, including a "giant neodymium wheel".Bis(amidinate) ligands in early lanthanide chemistry - synthesis, structures, and hydroamination catalysis.Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines.Ceric Cyclopentadienides Bearing Alkoxy, Aryloxy, Chlorido, or Iodido Co-Ligands.Asymmetrically substituted triazenes as poor electron donor ligands in the precursor chemistry of iron(ii) for iron-based metallic and intermetallic nanocrystals.Rare-earth metal-mediated PhC[triple bond, length as m-dash]N insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion - a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand.Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates.Five Rare μ4 -O-Centered Ln6 Clusters with Single-Molecule Magnet Behavior for Dy6.Enhancing the Value of Free Metals in the Synthesis of Lanthanoid Formamidinates: Is a Co-oxidant Needed?Palladium-catalyzed three-component reaction of N-tosyl hydrazones, isonitriles and amines leading to amidines.Insertion/Rearrangement Reactivity of a Lutetacyclopentadiene towards N,N'-Diphenylcarbodiimide: Cooperative Effect of the Metal Center, Concentration of LiCl, and Solvent.Novel inorganic heterocycles from dimetalated carboranylamidinates.Bis(alkyl) rare-earth complexes coordinated by bulky tridentate amidinate ligands bearing pendant Ph2P[double bond, length as m-dash]O and Ph2P[double bond, length as m-dash]NR groups. Synthesis, structures and catalytic activity in stereospecific iSynthesis and characterisation of magnesium complexes containing sterically demanding N,N'-bis(aryl)amidinate ligands.Inserted products of lithium silylquinolylamide dimers [{8-(2-R-C9H5N)N(Me3Si)}Li·OEt2]2 (R = H or Me) with dimethylcyanamide and their reactive derivatives with metal halides.Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerization.Reactivity of functionalized indoles with rare-earth metal amides. Synthesis, characterization and catalytic activity of rare-earth metal complexes incorporating indolyl ligands.Synthesis of γ-amidine-functionalized dianionic β-diketiminato lanthanide amides and trianionic β-diketiminato Na/Sm heterobimetallic complexes and their reactivity in polymerization of L-lactide.Sc2O3, Er2O3, and Y2O3 thin films by MOCVD from volatile guanidinate class of rare-earth precursors.Surprisingly Different Reaction Behavior of Alkali and Alkaline Earth Metal Bis(trimethylsilyl)amides toward Bulky N-(2-Pyridylethyl)-N'-(2,6-diisopropylphenyl)pivalamidine.Heteroleptic Guanidinate- and Amidinate-Based Complexes of Hafnium as New Precursors for MOCVD of HfO2Synthesis and structural characterization of four di-chlorido-bis-(cyclo-propyl-alkynyl-amidine)-metal complexes
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P2860
Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 08 April 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@en
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@nl
type
label
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@en
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@nl
prefLabel
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@en
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@nl
P356
P1476
Lanthanide amidinates and guan ...... r rare-earth oxide thin films.
@en
P2093
Frank T Edelmann
P304
P356
10.1039/B800100F
P577
2009-04-08T00:00:00Z