Gold and platinum catalysis--a convenient tool for generating molecular complexity.
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A ligand-directed divergent catalytic approach to establish structural and functional scaffold diversity.Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene.Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (L11(AuCl)), 933752 (L12(AuCl)a), 933753 (L9(AuCl)), 933754 (L10(AuCl)), 933756 (L8(AuCl)), 933757 (L12(AStoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp2)-H arylation.Gold-catalyzed diastereoselective cycloisomerization of alkylidene-cyclopropane-bearing 1,6-diynesGold for C-C coupling reactions: a Swiss-Army-knife catalyst?On the silver effect and the formation of chloride-bridged digold complexes.Gold catalysis: catalyst oxidation state dependent dichotomy in the cyclization of furan-yne systems with aromatic tethers.Gold(I)-catalyzed diastereo- and enantioselective 1,3-dipolar cycloaddition and Mannich reactions of azlactones.Phosphoramidite gold(I)-catalyzed diastereo- and enantioselective synthesis of 3,4-substituted pyrrolidinesA dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysisA racemic formal total synthesis of clavukerin A using gold(I)-catalyzed cycloisomerization of 3-methoxy-1,6-enynes as the key strategy.Combinatorial approach to chiral tris-ligated carbophilic platinum complexes: application to asymmetric catalysis.Experimental and computational evidence for gold vinylidenes: generation from terminal alkynes via a bifurcation pathway and facile C-H insertionsMechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.Catalytic coupling of arene C-H bonds and alkynes for the synthesis of coumarins: substrate scope and application to the development of neuroimaging agents.Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes.Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenesCatalytic enantioselective cyclization and C3-fluorination of polyenes.Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst.Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl estersMechanism of the Transmetalation of Organosilanes to Gold.Gold-Catalyzed Intramolecular Cyclizations of Cyclopropenes with Propargylic Esters.σ-π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis.Gold (III) Chloride-Catalyzed 6-endo-trig Oxa-Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones.Stereo- and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides.A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes.Highly Stereoselective Synthesis of Polycyclic Indoles through Rearrangement/[4+2] Cycloaddition under Sequential Catalysis.Silver(I)-Catalyzed Intramolecular Cyclizations of Epoxide-Propargylic Esters to 1,4-Oxazine Derivatives.Cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst.Gold-catalyzed enantioselective ring-expanding cycloisomerization of cyclopropylidene bearing 1,5-enynes.Gold-mediated C-H bond functionalisation.When cyclopropenes meet gold catalysts.When gold can do what iodine cannot do: A critical comparison.Recent developments in gold-catalyzed cycloaddition reactions.Enantioselective, transition metal catalyzed cycloisomerizations.Chirality transfer and memory of chirality in gold-catalyzed reactions.Axial-to-central chirality transfer in cyclization processes.Intriguing mechanistic labyrinths in gold(I) catalysis.Synthesis of heterocycles via transition-metal-catalyzed hydroarylation of alkynes.
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Gold and platinum catalysis--a convenient tool for generating molecular complexity.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
gotara zanistî
@ku-latn
scientific article published on 22 July 2009
@en
vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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name
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@en
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@nl
type
label
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@en
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@nl
prefLabel
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@en
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@nl
P356
P1476
Gold and platinum catalysis--a convenient tool for generating molecular complexity.
@en
P304
P356
10.1039/B816696J
P577
2009-07-22T00:00:00Z