Advances in selective activation and application of ammonia in homogeneous catalysis.
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On-line Ammonia Sensor and Invisible Security Ink by Fluorescent Zwitterionic Spirocyclic Meisenheimer Complex.Activation and coordination of ammonia at [Cp*Ir(H)2]: NMR and matrix isolation studies.Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.C-N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise.Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.Analysis of potential molecular catalysts for the hydroamination of ethylene with ammonia: a DFT study with [Ir(PCP)] and [Ir(PSiP)] complexes.Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2.An examination of the palladium/Mor-DalPhos catalyst system in the context of selective ammonia monoarylation at room temperature.Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine.Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine.Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine.Reactivity of the parent amido complexes of iridium with olefins: C-NH2 bond formation versus C-H activation.Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2.Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium.C-NH2 bond formation mediated by iridium complexes.P-H activation of secondary phosphanes on a parent amido diiridium complex.Iron catalyzed efficient synthesis of poly-functional primary amines via the direct use of ammonia.Platinum-catalyzed direct amination of allylic alcohols with aqueous ammonia: selective synthesis of primary allylamines.Understanding the reaction mechanism of the oxidative addition of ammonia by (PXP)Ir(i) complexes: the role of the X group.Stereoselective Pd(0) catalysed five component cascade synthesis of complex Z,Z-bisallylamines.Single and double N-H bond activation of ammonia by [Al2O3 ]˙+: room temperature formation of the aminyl radical and nitrene.Efficient and selective gas-phase monomethylation versus N-H bond activation of ammonia by "bare" Zn(CH3)+: atomic zinc as a leaving group in an SN2 reaction.Thermal activation of N-H bonds by transition-metal oxide cations: does a hierarchy exist in the first row?N-H bond activation by palladium(II) and copper(I) complexes featuring a reactive bidentate PN-ligand.Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium.Unusual N-H activation of 2-aminopyrimidine: supramolecular assembly into an Ag(I) metal-organic framework.BippyPhos: a single ligand with unprecedented scope in the Buchwald-Hartwig amination of (hetero)aryl chlorides.Germanium(iii) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activationsHeterolytic cleavage of ammonia N–H bond by bifunctional activation in silica-grafted single site Ta(V) imido amido surface complex. Importance of the outer sphere NH3 assistance
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Advances in selective activation and application of ammonia in homogeneous catalysis.
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article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 26 April 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Advances in selective activation and application of ammonia in homogeneous catalysis.
@en
Advances in selective activation and application of ammonia in homogeneous catalysis.
@nl
type
label
Advances in selective activation and application of ammonia in homogeneous catalysis.
@en
Advances in selective activation and application of ammonia in homogeneous catalysis.
@nl
prefLabel
Advances in selective activation and application of ammonia in homogeneous catalysis.
@en
Advances in selective activation and application of ammonia in homogeneous catalysis.
@nl
P356
P1476
Advances in selective activation and application of ammonia in homogeneous catalysis.
@en
P2093
Jarl Ivar van der Vlugt
P304
P356
10.1039/B925794M
P577
2010-04-26T00:00:00Z