Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
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Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and DienesA theoretically-guided optimization of a new family of modular P,S-ligands for iridium-catalyzed hydrogenation of minimally functionalized olefins.Ferrocenyl chiral bisphosphorus ligands for highly enantioselective asymmetric hydrogenation via noncovalent ion pair interaction.An additional coordination group leads to extremely efficient chiral iridium catalysts for asymmetric hydrogenation of ketones.Catalyst development for organocatalytic hydrosilylation of aromatic ketones and ketimines.Brønsted acid activation strategy in transition-metal catalyzed asymmetric hydrogenation of N-unprotected imines, enamines, and N-heteroaromatic compounds.Modulation of multifunctional N,O,P ligands for enantioselective copper-catalyzed conjugate addition of diethylzinc and trapping of the zinc enolate.Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides.Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed HydroaminationCopper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective HydrocuprationAn investigation of the observed, but counter-intuitive, stereoselectivity noted during chiral amine synthesis via N-chiral-ketimines.Synthesis of Cyclic α-Aminophosphonates through Copper Catalyzed Enamine ActivationLigand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Hydrogenation of imino bonds with half-sandwich metal catalysts.Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines.Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs.Homogeneous palladium-catalyzed asymmetric hydrogenation.Combining transition metal catalysis and organocatalysis--an update.Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions.Transition-Metal-Catalyzed Asymmetric Hydrogenation and Transfer Hydrogenation: Sustainable Chemistry to Access Bioactive Molecules.Kinetic Resolution of Benzylamines via Palladium(II)-Catalyzed C-H Cross-Coupling.Highly Enantioselective Iridium-Catalyzed Hydrogenation of Cyclic Enamides.Enantioselective Rh-Catalyzed Carboacylation of C═N Bonds via C-C Activation of Benzocyclobutenones.Hydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity.Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.Rhodium-catalyzed spirocyclic sultam synthesis by [3+2] annulation with cyclic N-sulfonyl ketimines and alkynes.Design of phosphorus ligands with deep chiral pockets: practical synthesis of chiral β-arylamines by asymmetric hydrogenation.Synthesis of chiral aliphatic amines through asymmetric hydrogenation.Asymmetric hydrogenation of isoquinolinium salts catalyzed by chiral iridium complexes: direct synthesis for optically active 1,2,3,4-tetrahydroisoquinolines.Catalytic enantioselective amination of alcohols by the use of borrowing hydrogen methodology: cooperative catalysis by iridium and a chiral phosphoric acid.Palladium-catalyzed oxidative carbonylation of the alkenyl C-H bonds of enamides: synthesis of 1,3-oxazin-6-ones.General and highly efficient iron-catalyzed hydrogenation of aldehydes, ketones, and α,β-unsaturated aldehydes.Palladium-catalyzed asymmetric hydrogenation of α-acyloxy-1-arylethanones.Magnesium catalysis of imine hydroboration.The use of phosphite-type ligands in the Ir-catalyzed asymmetric hydrogenation of heterocyclic compounds.Rh-catalyzed highly enantioselective hydrogenation of nitroalkenes under basic conditions.Imine hydrogenation by alkylaluminum catalysts.Highly enantioselective [3+3] cycloaddition of aromatic azomethine imines with cyclopropanes directed by π-π stacking interactions.A highly active cyclometallated iridium catalyst for the hydrogenation of imines.Triply Halide-Bridged Dinuclear Iridium(III) Complexes with Chiral Diphosphine Ligands as New Easy-to-Handle Iridium Catalysts for Asymmetric Hydrogenation of Imines and N-Heteroaromatics.
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P2860
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 17 December 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@en
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@nl
type
label
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@en
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@nl
prefLabel
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@en
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@nl
P2093
P356
P1433
P1476
Transition metal-catalyzed enantioselective hydrogenation of enamines and imines.
@en
P2093
Jian-Hua Xie
Qi-Lin Zhou
Shou-Fei Zhu
P304
P356
10.1021/CR100218M
P577
2010-12-17T00:00:00Z