Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals.
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Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and DienesFast, greener and scalable direct coupling of organolithium compounds with no additional solventsContribution of microreactor technology and flow chemistry to the development of green and sustainable synthesisTransition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates.Carboxylation of Phenols with CO2 at Atmospheric Pressure."Black Swan events" in organic synthesis.Divergent synthesis of novel 9-deazaxanthine derivatives via late-stage cross-coupling reactions.Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates.Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link.Modulation of multifunctional N,O,P ligands for enantioselective copper-catalyzed conjugate addition of diethylzinc and trapping of the zinc enolate.γ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine•borane adducts.A general method for copper-catalyzed arene cross-dimerizationTuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.Gold-catalyzed three-component spirocyclization: a one-pot approach to functionalized pyrazolidines.Dosage delivery of sensitive reagents enables glove-box-free synthesis.New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries.Enantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadieneAn Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Practical Organocatalytic Synthesis of Functionalized Non-C2-Symmetrical Atropisomeric Biaryls.Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.A general, practical palladium-catalyzed cyanation of (hetero)aryl chlorides and bromides.Palladium-catalyzed acetylation of arenesHighly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides.Symmetry in Cascade Chirality-Transfer Processes: A Catalytic Atroposelective Direct Arylation Approach to BINOL Derivatives.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.High-valent organometallic copper and palladium in catalysis.Addressing challenges in palladium-catalyzed cross-coupling reactions through ligand design.Industrial applications of the Diels-Alder reaction.On the way towards greener transition-metal-catalyzed processes as quantified by E factors.The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations.Hypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.Copper-catalysed cross-coupling: an untapped potential.Design, Synthesis, and Validation of an Effective, Reusable Silicon-Based Transfer Agent for Room-Temperature Pd-Catalyzed Cross-Coupling Reactions of Aryl and Heteroaryl Chlorides with Readily Available Aryl Lithium Reagents.Stereospecific functionalizations and transformations of secondary and tertiary boronic esters.Dinuclear Pd(I) complexes with bridging allyl and related ligands.Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.Acylboranes: synthetic strategies and applications.Annulative π-Extension (APEX): Rapid Access to Fused Arenes, Heteroarenes, and Nanographenes.Supported Ionic Liquids: A Versatile and Useful Class of Materials.
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Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on March 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@en
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@nl
type
label
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@en
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@nl
prefLabel
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@en
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@nl
P356
P1433
P1476
Large-scale applications of tr ...... synthesis of pharmaceuticals.
@en
P2093
Javier Magano
Joshua R Dunetz
P304
P356
10.1021/CR100346G
P577
2011-03-01T00:00:00Z