Magical power of transition metals: past, present, and future (Nobel Lecture).
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Synthesis and Reactivity of TriazaphenanthrenesPd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materialsHighly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-Cu- or Pd-catalyzed cross-coupling.Network-analysis-guided synthesis of weisaconitine D and liljestrandinine.Iron-catalysed cross-coupling of organolithium compounds with organic halides.Practical carbon-carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation.Rhodium-catalyzed boron arylation of 1,2-azaborinesSearch for highly efficient, stereoselective, and practical synthesis of complex organic compounds of medicinal importance as exemplified by the synthesis of the C21-C37 fragment of amphotericin B.Widely applicable synthesis of enantiomerically pure tertiary alkyl-containing 1-alkanols by zirconium-catalyzed asymmetric carboalumination of alkenes and palladium- or copper-catalyzed cross-coupling.Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I).Chemical structure, biosynthesis and synthesis of free and glycosylated pyridinolines formed by cross-link of bone and synovium collagen.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Cascade catalysis--strategies and challenges en route to preparative synthetic biology.Pd-mediated rapid cross-couplings using [(11) C]methyl iodide: groundbreaking labeling methods in (11) C radiochemistry.Copper-catalysed cross-coupling: an untapped potential.Indenylmetal Catalysis in Organic Synthesis.Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts.Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C-H Bonds of N-Aryl-2-amino Pyridine Derivatives.Direct heteroarylation polymerization: guidelines for defect-free conjugated polymers.Breaking Amides using Nickel Catalysis.Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides.Reactivity of Tp(Me2) -supported yttrium alkyl complexes toward aromatic N-heterocycles: ring-opening or C-C bond formation directed by C-H activation.Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki-Miyaura Coupling.Transition-metal-free chemo- and regioselective vinylation of azaallyls.Enhanced π-Back-Donation as a Way to Higher Coordination Numbers in d10 [M(NHC)n ] Complexes: A DFT Study.Exploring the Oxidative-Addition Pathways of Phenyl Chloride in the Presence of Pd(II) Abnormal N-Heterocyclic Carbene Complexes: A DFT Study.Phosphane-functionalized cycloheptatrienyl-cyclopentadienyl titanium sandwich complexes: phosphorus ligands with an integrated reducing agent for palladium(0) catalyst generation.Computed ligand effects on the oxidative addition of phenyl halides to phosphine supported palladium(0) catalysts.Exploring the emergence of complexity using synthetic replicators.Direct arylation of inactivated benzene with aryl acyl peroxides toward biaryls.Selective C-H and C-C Bond Activation: Electronic Regimes as a Tool for Designing d(10) MLn Catalysts.Fast, Efficient and Low E-Factor One-Pot Palladium-Catalyzed Cross-Coupling of (Hetero)Arenes.Pd-mediated cross-coupling of C-17 lithiated androst-16-en-3-ol - access to functionalized arylated steroid derivatives.Oxygen Activated, Palladium Nanoparticle Catalyzed, Ultrafast Cross-Coupling of Organolithium Reagents.Phenyltrimethylammonium Salts as Methylation Reagents in the Nickel-Catalyzed Methylation of C-H Bonds.One-Pot Halogen Dance/Negishi Coupling of Dibromothiophenes for Regiocontrolled Synthesis of Multiply Arylated Thiophenes.Weinreb amide directed cross-coupling reaction between electron-deficient alkenes catalyzed by a rhodium catalyst.Programmed Site-Selective Palladium-Catalyzed Arylation of Thieno[3,2-b]thiophene.Efficient synthesis of benzocyclotrimer analogues by Negishi cross-coupling and intramolecular nucleophilic substitution.
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P2860
Magical power of transition metals: past, present, and future (Nobel Lecture).
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 29 June 2011
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Magical power of transition metals: past, present, and future (Nobel Lecture).
@en
Magical power of transition metals: past, present, and future (Nobel Lecture).
@nl
type
label
Magical power of transition metals: past, present, and future (Nobel Lecture).
@en
Magical power of transition metals: past, present, and future (Nobel Lecture).
@nl
prefLabel
Magical power of transition metals: past, present, and future (Nobel Lecture).
@en
Magical power of transition metals: past, present, and future (Nobel Lecture).
@nl
P356
P1476
Magical power of transition metals: past, present, and future (Nobel Lecture).
@en
P304
P356
10.1002/ANIE.201101380
P407
P577
2011-06-29T00:00:00Z