N-tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions.
about
Palladium-Catalyzed Multi-Component Reactions of N-Tosylhydrazones, 2-Iodoanilines and CO2 towards 4-Aryl-2-Quinolinones.Arylation of rhodium(II) azavinyl carbenes with boronic acids.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.Recent approaches for C-C bond formation via direct dehydrative coupling strategies.To be or not to be metal-free: trends and advances in coupling chemistries.Recent advances in transition-metal-catalyzed synthesis of conjugated enynes.New Approaches to the Synthesis of Metal Carbenes.Recent Advances in the Synthesis of Heterocycles and Related Substances Based on α-Imino Rhodium Carbene Complexes Derived from N-Sulfonyl-1,2,3-triazoles.An entry to vinylcyclopropane through palladium-catalyzed intramolecular cyclopropanation of alkenes with unstabilized allylic tosylhydrazones.An efficient coupling of N-tosylhydrazones with 2-halopyridines: synthesis of 2-α-styrylpyridines endowed with antitumor activity.N-Tosylhydrazones: versatile synthons in the construction of cyclic compounds.The synthesis of cardenolide and bufadienolide aglycones, and related steroids bearing a heterocyclic subunit.Synthesis, biological evaluation, and structure-activity relationships of tri- and tetrasubstituted olefins related to isocombretastatin A-4 as new tubulin inhibitors.Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of α-diazo carbonyls via radical dediazotization.Gold(I) carbenes by retro-Buchner reaction: generation and fate.Facile synthesis of dibranched conjugated dienes via palladium-catalyzed oxidative coupling of N-tosylhydrazones.Catalyst-free intramolecular formal carbon insertion into σ-C-C bonds: a new approach toward phenanthrols and naphthols.Copper-mediated synthesis of 1,2,3-triazoles from N-tosylhydrazones and anilines.An easy access to fluoroalkanes by deoxygenative hydrofluorination of carbonyl compounds via their tosylhydrazones.Palladium-catalyzed Suzuki cross-coupling of N'-tosyl arylhydrazines.Conversion of Triple Bonds into Single Bonds in a Domino Carbopalladation with Norbornene.Catalytic Synthesis of Indolines by Hydrogen Atom Transfer to Cobalt(III)-Carbene Radicals.Alkynyl N-Nosylhydrazones: Easy Decomposition to Alknynl Diazomethanes and Application in Allene Synthesis.α-Diazo oxime ethers for N-heterocycle synthesis.Synthesis of (Z)-N-alkenylazoles and pyrroloisoquinolines from α-N-azoleketones through Pd-catalyzed tosylhydrazone cross-couplings.Mechanism of the rhodium(iii)-catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a computational study.Regioselective one-step synthesis of pyrazoles from alkynes and N-tosylhydrazones: [3+2] dipolar cycloaddition/[1,5] sigmatropic rearrangement cascade.Rh(V) -Nitrenoid as a Key Intermediate in Rh(III) -Catalyzed Heterocyclization by C-H Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds.Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.Multi-Component One-Pot Reaction of Aromatic Carbonyl Compounds, Tosylhydrazide, and Arylboronic Acids.Copper- or Thermally Induced Divergent Outcomes: Synthesis of 4-Methyl 2H-Chromenes and Spiro-4H-Pyrazoles.Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2 )-H Bonds: Access to Substituted 1H-Indenes.Iron-catalyzed intermolecular cycloaddition of diazo surrogates with hexahydro-1,3,5-triazines.Zinc-promoted cyclization of tosylhydrazones and 2-(dimethylamino)malononitrile: an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles.Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids.Silver-Catalyzed [2+1] Cyclopropenation of Alkynes with Unstable Diazoalkanes: N-Nosylhydrazones as Room-Temperature Decomposable Diazo Surrogates.C[double bond, length as m-dash]N bond formation via palladium-catalyzed carbene insertion into N[double bond, length as m-dash]N bonds: inhibiting the general 1,2-migration process of ylide intermediates.Silver(i)-promoted insertion into X-H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones.Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)-Carbene Radical and ortho-Quinodimethane Intermediates.Dual rhodium/copper catalysis: synthesis of benzo[b]fluorenes and 2-naphthalenylmethanones via de-diazotized cycloadditions.
P2860
Q33469109-0632CAAC-605F-460E-8A7A-80CEBDC0D5F7Q36683776-DB1D2845-5DF1-4FBC-B1C5-9384199571B0Q37714497-19EEE747-B66C-4DB0-A0CA-B7DF098B51F9Q38063394-E850EB68-54F8-4171-8E73-BD172798EF8BQ38161784-9228C7ED-8CB8-4675-981E-D6AC756174E2Q38862551-4CE5E7C9-9A8A-4EB2-AEB0-CE5C66313748Q38867130-791C65ED-7E9A-4069-8DB2-EB88B35FF26BQ38894413-BF5FB809-C1A5-40F5-8AFD-6D2F6BF0C224Q39031253-CBEC9CC3-B65E-4AE6-8567-540A93778576Q39161057-63756958-FD5A-4C9D-BEC0-5F03211F7D44Q39204043-B8AD9565-D8AA-44D0-8956-C45ECE6A7E68Q39221272-036FC64A-5D36-47E0-905C-D594A49101A4Q39263355-A3B46AE8-1088-4171-8A10-21F1821097A2Q39820733-21C97111-98FE-4077-9AE7-3216BD6521CCQ41885109-518D22FF-CC50-43FC-B13B-9E2480008251Q43753376-DC5236BB-91FD-4BCE-999B-2E652782A1BFQ44826496-B016B2F1-944F-4DAF-B482-DC44AA8448BEQ44891548-4DC7D08B-699D-47ED-8BA9-0ADC0866DE35Q45128362-CCECD32D-5903-403A-A05C-08310704D9E2Q45327449-93439D96-AE32-450C-8D3E-2A0ADDCF0E3FQ46277497-1519DAF9-39DD-4992-9CB2-9B05C888FEF7Q46313760-003E34C4-26AB-4095-8DDD-72AD3212AD7FQ46360357-2667F9B6-6AF1-45D2-97A5-81F9F316E444Q46364279-9E04954F-47D8-4D0F-A07A-BB2E2D4A174BQ46471871-C038CF7B-66CA-4084-AD96-CD4CFED34669Q46562516-6944AD8B-76C4-4C2E-BB12-896296F13C07Q46695317-A42D68ED-9CA6-4061-9E79-DE34FC0AD066Q46727591-0FAED6D5-E5F6-48A6-8FD3-8883E6146A8AQ47200931-5977C041-5C3E-4F8F-A5D2-D220B5D1263AQ47273246-C0510BBD-BEC4-4C54-A635-157855A1A61FQ47374960-AB8B0DD2-044B-48B0-B213-0FDC6C6B0CD3Q47409040-365EA27D-B9B8-4712-B679-FD90E9B8764FQ47700387-70F64181-D20A-4E4B-B479-93F07372DCFBQ47925220-1C7EA560-7A13-4F32-8928-E383B42FEEBDQ47949592-C9875EF7-477E-4BCF-B683-34FE95776CA6Q48146206-2A959C3C-4960-4A0E-BC9A-07856D386BDAQ48237141-98AA8014-8E48-4ECA-A6FB-0244206A331DQ48254615-A07413DF-681E-47FE-AC30-082EF1E37637Q48272138-0F94D7E6-BB7D-483C-8B9B-117CA000356BQ48313066-14D50DDC-E389-4C7F-91D7-4F14ACF3B242
P2860
N-tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 25 July 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@en
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@nl
type
label
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@en
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@nl
prefLabel
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@en
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@nl
P356
P1476
N-tosylhydrazones: versatile r ...... free cross-coupling reactions.
@en
P2093
Hongbin Zhang
Zhihui Shao
P304
P356
10.1039/C1CS15127D
P577
2011-07-25T00:00:00Z