A comprehensive history of arynes in natural product total synthesis.
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Synthesis of Oxygen Heterocycles via Aromatic C-O Bond Formation Using ArynesNitrone Cycloadditions of 1,2-CyclohexadieneCYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDDA) REACTIONQuantification of the Electrophilicity of Benzyne and Related Intermediates.Gold-catalyzed cyclizations of cis-enediynes: insights into the nature of gold-aryne interactions.Mechanism of the reactions of alcohols with o-benzynes.Cycloadditions of cyclohexynes and cyclopentyneThe role of aryne distortions, steric effects, and charges in regioselectivities of aryne reactionsGeneral method for functionalized polyaryl synthesis via aryne intermediates.Computational predictions of substituted benzyne and indolyne regioselectivities.Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through C-H Activation and Orthogonal Reactivity.Promoting C-C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt-CH3(+) Complexes.A Practical, Multi-gram Synthesis of (±)-Herbindole A, (±)-Herbindole B, and (±)-Herbindole C from a Common Intermediate via 6,7-Indole Aryne Cycloaddition and Pd(0)-Catalyzed Cross-Coupling Reactions.Generation and regioselective trapping of a 3,4-piperidyne for the synthesis of functionalized heterocycles.1,2-Azaborine: The Boron-Nitrogen Derivative of ortho-BenzyneTriple Aryne-Tetrazine Reaction Enabling Rapid Access to a New Class of Polyaromatic HeterocyclesSteric effects compete with aryne distortion to control regioselectivities of nucleophilic additions to 3-silylarynes.Palladium-catalyzed annulation of arynes by o-halobenzamides: synthesis of phenanthridinones.Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model.The hexadehydro-Diels-Alder reactionCycloaddition of Arynes and Cyclic Enol Ethers as a Platform for Access to Stereochemically Defined 1,2-Disubstituted BenzocyclobutenesAlkane desaturation by concerted double hydrogen atom transfer to benzyneCatalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of DioxasilinesReactions of HDDA-Derived Benzynes with Sulfides: Mechanism, Modes, and Three-Component Reactions.Synthesis of complex benzenoids via the intermediate generation of o-benzynes through the hexadehydro-Diels-Alder reaction.Concise enantiospecific total synthesis of tubingensin A.Total synthesis of the pseudopterosin aglycones.Reactions of arynes promoted by silver ions.Application of the aza-Diels-Alder reaction in the synthesis of natural products.Insertion of arynes into N-halo bonds: a direct approach to o-haloaminoarenes.Synthesis of biaryls using aryne intermediates.Aryne multifunctionalization with benzdiyne and benztriyne equivalents.Double heteroatom functionalization of arenes using benzyne three-component coupling.Silylaryl Halides Can Replace Triflates as Aryne Precursors.Reductive Deamination by Benzyne for Deoxy Sugar Synthesis Through a Domino ReactionIndole diterpenoid natural products as the inspiration for new synthetic methods and strategiesRapid access to substituted 2-naphthyne intermediates via the benzannulation of halogenated silylalkynesBlue-Emitting Arylalkynyl Naphthalene Derivatives via a Hexadehydro-Diels-Alder Cascade Reaction.The hexadehydro-Diels-Alder reaction: a new chapter in aryne chemistry.Temporary intramolecular generation of pyridine carbenes in metal-free three-component C-H bond functionalisation/aryl-transfer reactions.
P2860
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P2860
A comprehensive history of arynes in natural product total synthesis.
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
@pt
artigo científico
@pt-br
artikel ilmiah
@id
artikull shkencor
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artículo científico
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name
A comprehensive history of arynes in natural product total synthesis.
@en
A comprehensive history of arynes in natural product total synthesis.
@nl
type
label
A comprehensive history of arynes in natural product total synthesis.
@en
A comprehensive history of arynes in natural product total synthesis.
@nl
prefLabel
A comprehensive history of arynes in natural product total synthesis.
@en
A comprehensive history of arynes in natural product total synthesis.
@nl
P356
P1433
P1476
A comprehensive history of arynes in natural product total synthesis.
@en
P2093
Brian M Stoltz
Pamela M Tadross
P304
P356
10.1021/CR200478H
P577
2012-03-23T00:00:00Z