Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
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The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Chiral phosphines in nucleophilic organocatalysisNucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric AnnulationsRecent advances in organocatalytic methods for asymmetric C-C bond formation.Morita-Baylis-Hillman adduct derivatives (MBHADs): versatile reactivity in Lewis base-promoted annulation.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction.Organocatalytic asymmetric allylic amination of Morita-Baylis-Hillman carbonates of isatins.Asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with α-fluoro-β-keto esters.Morita-Baylis-Hillman reaction of acrylamide with isatin derivatives.Phosphine-catalyzed [3 + 2] cycloaddition of Morita-Baylis-Hillman carbonates with sulfamate-derived cyclic imines.Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita-Baylis-Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines.Baylis-Hillman bromides as a source of 1,3-dipoles: sterically directed synthesis of oxindole-fused spirooxirane and spirodihydrofuran frameworks.Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted C-F bond cleavage.Lewis base catalyzed asymmetric substitution/Diels-Alder cascade reaction: a rapid and efficient construction of enantioenriched diverse tricyclic heterocycles.Chemo- and Stereoselective Cross Rauhut-Currier-Type Reaction of Tri-substituted Alkenes Containing Trifluoromethyl Groups.Morita-Baylis-Hillman Reaction of β,β-Disubstituted Enones: An Enantioselective Organocatalytic Approach for the Synthesis of Cyclopenta[b]annulated Arenes and Heteroarenes.Asymmetric Morita-Baylis-Hillman Reaction: Catalyst Development and Mechanistic Insights Based on Mass Spectrometric Back-Reaction Screening.Palladium-Catalyzed Asymmetric Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters by Allylation of β-Ketocarbonyls with Morita-Baylis-Hillman Adducts.Multifunctional chiral phosphine-catalyzed [3+2] annulation of Morita-Baylis-Hillman carbonates with cyclopentenones: asymmetric synthesis of 4-oxo-hexahydropentalenes.Asymmetric P-C Bond Formation: Diastereoselective Synthesis of Adjacent P,C-Stereogenic Allylic Phosphorus Compounds.Highly regio- and diastereo-selective synthesis of novel tri- and tetra-cyclic perhydroquinoline architectures via an intramolecular [3 + 2] cycloaddition reaction.Novel organocatalytic activation of unmodified Morita-Baylis-Hillman alcohols for the synthesis of bicyclic α-alkylidene-ketones.Asymmetric aza-Morita-Baylis-Hillman reactions of chiral N-phosphonyl imines with acrylates via GAP chemistry/technology.Chiral phosphine catalyzed asymmetric Michael addition of oxindoles.Highly enantioselective synthesis of fused bicyclic dihydropyranones via low-loading N-heterocyclic carbene organocatalysis.Catalyst-controlled switch of regioselectivity in the asymmetric allylic alkylation of oxazolones with MBHCs.Organocatalytic enantioselective allylic alkylation of MBH carbonates with β-keto esters.A multicomponent cascade reaction for the synthesis of novel chromenopyranpyrazole scaffolds.Highly stereoselective construction of adjacent tetrasubstituted carbon stereogenic centres via an organocatalytic Mukaiyama-aldol reaction of monofluorinated silyl enol ethers to isatins
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P2860
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
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article científic
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article scientifique
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articol științific
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articolo scientifico
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artigo científico
@gl
artigo científico
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artigo científico
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artikel ilmiah
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artículo científico
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name
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@en
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@nl
type
label
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@en
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@nl
prefLabel
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@en
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@nl
P2093
P2860
P356
P1476
Organocatalytic asymmetric transformations of modified Morita-Baylis-Hillman adducts.
@en
P2093
Tian-Yu Liu
Ying-Chun Chen
P2860
P304
P356
10.1039/C2CS35017C
P577
2012-03-28T00:00:00Z