Transfer of chirality from ligands to metal centers: recent examples.
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Comparison of the electronic and vibrational optical activity of a europium(III) complex.Spin crossover properties of enantiomers, co-enantiomers, racemates, and co-racemates.Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenesConformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding.Coordination chemistry strategies for dynamic helicates: time-programmable chirality switching with labile and inert metal helicates.Asymmetric catalysis mediated by the ligand sphere of octahedral chiral-at-metal complexes.Tuning riboswitch-mediated gene regulation by rational control of aptamer ligand binding properties.A family of Fe(3+) based double-stranded helicates showing a magnetocaloric effect, and Rhodamine B dye and DNA binding activities.Thioether-based anchimeric assistance for asymmetric coordination chemistry with ruthenium(II) and osmium(II).Anion-driven reversible switching of metal-centered stereoisomers in metallopeptides.Assembly of helicene-capped N,P,N,P,N-helicands within Cu(I) helicates: impacting chiroptical properties by ligand-ligand charge transfer.Stereodynamics of metal-ligand assembly: what lies beneath the "simple" spectral signatures of C2-symmetric chiral chelates.Chirality transfer based on reversible C-C bond formation/breaking in nickel(II) complexes.Highly Phosphorescent Crystals of Square-Planar Platinum Complexes with Chiral Organometallic Linkers: Homochiral versus Heterochiral Arrangements, Induced Circular Dichroism, and TD-DFT Calculations.Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior.Synthesis, structure, magnetic and biological activity studies of bis-hydrazone derived Cu(ii) and Co(ii) coordination compounds.Terpenols as substituents for the diastereoselective formation of enantiomerically pure triple lithium-bridged helicate type-coordination compounds.Sign reversal of a large circularly polarized luminescence signal by the twisting motion of a bidentate ligand.Stereocontrol in dinuclear triple lithium-bridged titanium(IV) complexes: solving some stereochemical mysteries.Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion.Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies.Response speed control of helicity inversion based on a "regulatory enzyme"-like strategy.A stereodynamic fluorescent probe for amino acids. Circular dichroism and circularly polarized luminescence analysis.Multifunctionality in bimetallic Ln(III)[W(V)(CN)8]3- (Ln = Gd, Nd) coordination helices: optical activity, luminescence, and magnetic coupling.Enantioselective Alkynylation of 2-Trifluoroacetyl Imidazoles Catalyzed by Bis-Cyclometalated Rhodium(III) Complexes Containing Pinene-Derived Ligands.Bimetallic Gold(I) Complexes with Ethynyl-Helicene and Bis-Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties.Planar chiral iridium complexes with the Δ-TRISPHAT anion: toward the first enantiopure o-quinone methide π-complex.Expanding the family of bis-cyclometalated chiral-at-metal rhodium(iii) catalysts with a benzothiazole derivative.One-handed single helicates of dinickel(II) benzenehexapyrrole-α,ω-diimine with an amine chiral source.Chiral tetrahedral iron(II) cages: diastereoselective subcomponent self-assembly, structure interconversion and spin-crossover properties.The stereoselectivity of bipyrrolidine-based sequential polydentate ligands around Ru(ii).A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: combined chiroptical, magnetic, and nonlinear optical properties.Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines.Hydroxy-Directed Ruthenium-Catalyzed Alkene/Alkyne Coupling: Increased Scope, Stereochemical Implications, and Mechanistic RationaleAssembling Quasi-enantiomeric Octahedral Complexes of Different Metals via Quasi-racemate CrystallizationZinc Complexes of Bipyrrolidine-Based Diamine-Diphenolato and Diamine-Diolato Ligands: Predetermination of Helical Chirality Around Tetrahedral CentresLanthanide supramolecular helical diastereoselective breaking induced by point chirality: mixture or P-helix, M-helixNovel ortho-OPE metallofoldamers: binding-induced folding promoted by nucleating Ag(i)–alkyne interactions
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P2860
Transfer of chirality from ligands to metal centers: recent examples.
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article científic
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article scientifique
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articol științific
@ro
articolo scientifico
@it
artigo científico
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artigo científico
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artigo científico
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artikel ilmiah
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artikull shkencor
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artículo científico
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name
Transfer of chirality from ligands to metal centers: recent examples.
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type
label
Transfer of chirality from ligands to metal centers: recent examples.
@en
prefLabel
Transfer of chirality from ligands to metal centers: recent examples.
@en
P2860
P356
P1476
Transfer of chirality from ligands to metal centers: recent examples.
@en
P2860
P304
P356
10.1039/C2CC31542D
P407
P577
2012-10-01T00:00:00Z