Radical cascades initiated by intermolecular radical addition to alkynes and related triple bond systems.
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Aerobic oxidation in nanomicelles of aryl alkynes, in water at room temperature.Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes.Radical cascade reaction of alkynes with N-fluoroarylsulfonimides and alcohols.The Cleavage of a C-C Bond in Cyclobutylanilines by Visible-Light Photoredox Catalysis: Development of a [4+2] Annulation Method.Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light PhotocatalysisConstructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis.Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation.Carbon-Centered Radical Addition to C=X Bonds for C-X Bond Formation.Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.Z-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes.Synthesis of carbonylated heteroaromatic compounds via visible-light-driven intramolecular decarboxylative cyclization of o-alkynylated carboxylic acids.A novel class of chemicals that react with abasic sites in DNA and specifically kill B cell cancers.Damage of polyesters by the atmospheric free radical oxidant NO3 (•): a product study involving model systems.Intermolecular oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes involving C(sp3)-H functionalization.Aerobic radical multifunctionalization of alkenes using tert-butyl nitrite and water.Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterAn approach to benzophosphole oxides through silver- or manganese-mediated dehydrogenative annulation involving C-C and C-P bond formation.Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes.Cascade nitrosation and addition-elimination of nitroacetanilides for the highly efficient synthesis of 1,4,2,5-dioxadiazine derivatives.A Copper-Catalyzed Aerobic [1,3]-Nitrogen Shift through Nitrogen-Radical 4-exo-trig Cyclization.Iron-Catalyzed Radical Decarboxylative Oxyalkylation of Terminal Alkynes with Alkyl Peroxides.Combining Traceless Directing Groups with Hybridization Control of Radical Reactivity: From Skipped Enynes to Defect-Free Hexagonal Frameworks.Thiyl radical-mediated cyclization of ω-alkynyl O-tert-butyldiphenylsilyloximes.Metal-Free Direct Alkylation of Ketene Dithioacetals by Oxidative C(sp2 )-H/C(sp3 )-H Cross-Coupling.Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes.Fused multifunctionalized dibenzoselenophenes from tetraynes.Solvent-Enabled Radical Selectivities: Controlled Syntheses of Sulfoxides and Sulfides.Synthesis of functionalized 5-substituted thiazolidine-2-thiones via adscititious xanthate-promoted radical cyclization of allyl(alkyl/aryl)dithiocarbamates.Reaction between Azidyl Radicals and Alkynes: A Straightforward Approach to NH-1,2,3-Triazoles.Copper-catalyzed cascade cyclization of 1,5-enynes via consecutive trifluoromethylazidation/diazidation and click reaction: self-assembly of triazole fused isoindolines.Copper-catalyzed oxidative [2+2+1] annulation of 1,n-enynes with α-carbonyl alkyl bromides through C-Br/C-H functionalization.Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)-H bonds and aryl C(sp2)-H bonds.Di-tert-butyl peroxide-mediated atom-transfer radical addition of 2-chlorodithiane to aryl alkynes under mild conditions.Metal-free oxidative radical addition of carbonyl compounds to α,α-diaryl allylic alcohols: synthesis of highly functionalized ketones.Cascade nitration/cyclization of 1,7-enynes with tBuONO and H2O: one-pot self-assembly of pyrrolo[4,3,2-de]quinolinones.Efficient synthesis of chiral cyclic acetals by metal and Brønsted acid co-catalyzed enantioselective four-component cascade reactions.Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes.Visible-light-induced radical cyclization of trifluoroacetimidoyl chlorides with alkynes: catalytic synthesis of 2-trifluoromethyl quinolines.The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational studyAerobic Radical-Cascade Alkylation/Cyclization of α,β-Unsaturated Amides: an Efficient Approach to Quaternary Oxindoles.
P2860
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P2860
Radical cascades initiated by intermolecular radical addition to alkynes and related triple bond systems.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
Radical cascades initiated by ...... d related triple bond systems.
@en
type
label
Radical cascades initiated by ...... d related triple bond systems.
@en
prefLabel
Radical cascades initiated by ...... d related triple bond systems.
@en
P356
P1433
P1476
Radical cascades initiated by ...... d related triple bond systems.
@en
P2093
P304
P356
10.1021/CR100359D
P577
2012-11-02T00:00:00Z