Diastereoselective allylation of carbonyl compounds and imines: application to the synthesis of natural products.
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Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent MechanismsEnantioselective synthesis of (Z)- and (E)-2-methyl-1,5-anti-pentenediols via an allene hydroboration-double-allylboration reaction sequence.Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.Recent Advances in Transition-Metal-Free Oxygenation of Alkene C=C Double Bonds for Carbonyl Generation.Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis.Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols.In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis.Arylative Intramolecular Allylation of Ketones with 1,3-Enynes Enabled by Catalytic Alkenyl-to-Allyl 1,4-Rhodium(I) Migration.3-Cyanoallyl boronates are versatile building blocks in the synthesis of polysubstituted thiophenes.Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control.Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and DiboranesCatalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters.Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters.Catalytic enantioselective protoboration of disubstituted allenes. Access to alkenylboron compounds in high enantiomeric purity.Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles.One pot conversion of benzophenone imine into the relevant 2-aza-allenium.Regioselective Transition-Metal-Free Allyl-Allyl Cross-Couplings.Titanium-catalyzed hydroalumination of conjugated dienes: access to fulvene-derived allylaluminium reagents and their diastereoselective reactions with carbonyl compounds.Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction.A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols Using Palladium and a Chiral Phosphoric Acid.Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones.Highly Enantioselective Allylation of Ketones: An Efficient Approach to All Stereoisomers of Tertiary Homoallylic Alcohols.Chiral Amino Alcohol Accelerated and Stereocontrolled Allylboration of Iminoisatins: Highly Efficient Construction of Adjacent Quaternary Stereogenic Centers.α-Trifluoromethylated tertiary homoallylic amines: diastereoselective synthesis and conversion into β-aminoesters, γ- and δ-aminoalcohols, azetidines and pyrrolidines.A Green Approach for Allylations of Aldehydes and Ketones: Combining Allylborate, Mechanochemistry and Lanthanide Catalyst.Copper-Catalyzed Borylcupration of Allenylsilanes.A highly enantioselective Hg(ii)-catalyzed Sakurai-Hosomi reaction of isatins with allyltrimethylsilanes.Highly Selective Addition of a Broad Spectrum of Trimethylsilane Pro-nucleophiles to N-tert-Butanesulfinyl Imines.Indium-catalysed amide allylation of α-iminoamide: highly enantioselective synthesis of amide functionalised α-methylene-γ-butyrolactams.Highly Diastereo- and Enantioselective Cu-Catalyzed Borylative Coupling of 1,3-Dienes and Aldimines.Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes.Recent Developments in the Chiral Brønsted Acid-catalyzed Allylboration Reaction with Polyfunctionalized Substrates.Hot water-promoted cyclopropylcarbinyl rearrangement facilitates construction of homoallylic alcohols.Oxidation of Hindered Allylic C–H Bonds with Applications to the Functionalization of Complex Molecules.Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters.Enantioselective Allylation of (2E,4E)-2,4-Dimethylhexadienal: Synthesis of (5R,6S)-(+)-PteroenoneBi-mediated allylation of aldehydes in [bmim][Br]: a mechanistic investigation
P2860
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P2860
Diastereoselective allylation of carbonyl compounds and imines: application to the synthesis of natural products.
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article científic
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article scientifique
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articol științific
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articolo scientifico
@it
artigo científico
@gl
artigo científico
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artigo científico
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artikel ilmiah
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artikull shkencor
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artículo científico
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name
Diastereoselective allylation ...... synthesis of natural products.
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type
label
Diastereoselective allylation ...... synthesis of natural products.
@en
prefLabel
Diastereoselective allylation ...... synthesis of natural products.
@en
P356
P1433
P1476
Diastereoselective allylation ...... synthesis of natural products.
@en
P2093
Francisco Foubelo
José C González-Gómez
P304
P356
10.1021/CR400008H
P50
P577
2013-03-29T00:00:00Z