Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.
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Chemo- and Stereoselective Cross Rauhut-Currier-Type Reaction of Tri-substituted Alkenes Containing Trifluoromethyl Groups.Catalytic Asymmetric 1,3-Dipolar Cycloaddition of β-Fluoroalkylated α,β-Unsaturated 2-Pyridylsulfones with Nitrones for Chiral Fluoroalkylated Isoxazolidines and γ-Amino Alcohols.Successive C-C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization.Access to benzo-fused nine-membered heterocyclic alkenes with a trifluoromethyl carbinol moiety via a double decarboxylative formal ring-expansion process under palladium catalysis.
P2860
Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.
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name
Catalytic asymmetric synthesis ...... ng a C-CF3 stereogenic center.
@en
type
label
Catalytic asymmetric synthesis ...... ng a C-CF3 stereogenic center.
@en
prefLabel
Catalytic asymmetric synthesis ...... ng a C-CF3 stereogenic center.
@en
P2093
P2860
P356
P1476
Catalytic asymmetric synthesis ...... ing a C-CF3 stereogenic center
@en
P2093
Yi-Yong Huang
P2860
P304
P356
10.1002/CHEM.201500361
P407
P577
2015-03-03T00:00:00Z