N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes
about
Radicals: Reactive Intermediates with Translational PotentialCatalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation.Cu-Catalyzed aromatic C-H imidation with N-fluorobenzenesulfonimide: mechanistic details and predictive modelsRecent synthetic additions to the visible light photoredox catalysis toolbox.A new era for homolytic aromatic substitution: replacing Bu3SnH with efficient light-induced chain reactions.New amination strategies based on nitrogen-centered radical chemistry.Photocatalysis in organic and polymer synthesis.Functionalization of C-H Bonds by Photoredox Catalysis.C-H imidation: a distinct perspective of C-N bond formation.Triiodide-Mediated δ-Amination of Secondary C-H Bonds.Non-directed aromatic C-H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent designIodine(III)-Mediated para-Selective Direct Imidation of Anilides.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesVisible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterPhotoredox ketone catalysis for the direct C-H imidation and acyloxylation of arenes.Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical-radical coupling.Charge-transfer-directed radical substitution enables para-selective C-H functionalization.Photoredox catalysis in a complex pharmaceutical setting: toward the preparation of JAK2 inhibitor LY2784544.Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions.Synthesis of Arylamines via Aminium Radicals.Copper(i)-catalyzed radical decarboxylative imidation of carboxylic acids with N-fluoroarylsulfonimides.Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.Photoredox Imino Functionalizations of Olefins.Visible-light-mediated C2-amination of thiophenes by using DDQ as an organophotocatalyst.Organophotocatalytic Generation of N- and O-Centred Radicals Enables Aerobic Oxyamination and Dioxygenation of Alkenes.Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis.Visible-Light Promoted Distereodivergent Intramolecular Oxyamidation of Alkenes.Teaching Old Compounds New Tricks: DDQ-Photocatalyzed C-H Amination of Arenes with Carbamates, Urea, and N-Heterocycles.Visible-Light-Induced Direct Oxidative C-H Amidation of Heteroarenes with Sulfonamides.Site-Selective Copper-Catalyzed Amination and Azidation of Arenes and Heteroarenes via Deprotonative Zincation.Catalytic substitution/cyclization sequences of O-substituted Isocyanates: synthesis of 1-alkoxybenzimidazolones and 1-alkoxy-3,4-dihydroquinazolin-2(1H)-ones.Nickel-catalyzed acetamidation and lactamization of arylboronic acids.Visible-light-promoted selective C-H amination of heteroarenes with heteroaromatic amines under metal-free conditions.Merging Visible-Light Photocatalysis and Palladium Catalysis for C-H Acylation of Azo- and Azoxybenzenes with α-Keto Acids.Sunlight-Driven Decarboxylative Alkynylation of α-Keto Acids with Bromoacetylenes by Hypervalent Iodine Reagent Catalysis: A Facile Approach to Ynones.Direct C-H difluoromethylenephosphonation of arenes and heteroarenes with bromodifluoromethyl phosphonate via visible-light photocatalysis.Site-selective arene C-H amination via photoredox catalysis.Visible-light-promoted iminyl-radical formation from acyl oximes: a unified approach to pyridines, quinolines, and phenanthridines.Photocatalytic generation of N-centered hydrazonyl radicals: a strategy for hydroamination of β,γ-unsaturated hydrazones.A Rhodium Catalyst Superior to Iridium Congeners for Enantioselective Radical Amination Activated by Visible Light.
P2860
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P2860
N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年論文
@yue
2014年論文
@zh-hant
2014年論文
@zh-hk
2014年論文
@zh-mo
2014年論文
@zh-tw
2014年论文
@wuu
2014年论文
@zh
2014年论文
@zh-cn
name
N-Acyloxyphthalimides as nitro ...... ion of arenes and heteroarenes
@en
N-Acyloxyphthalimides as nitro ...... on of arenes and heteroarenes.
@nl
type
label
N-Acyloxyphthalimides as nitro ...... ion of arenes and heteroarenes
@en
N-Acyloxyphthalimides as nitro ...... on of arenes and heteroarenes.
@nl
prefLabel
N-Acyloxyphthalimides as nitro ...... ion of arenes and heteroarenes
@en
N-Acyloxyphthalimides as nitro ...... on of arenes and heteroarenes.
@nl
P2093
P2860
P356
P1476
N-Acyloxyphthalimides as nitro ...... ion of arenes and heteroarenes
@en
P2093
Laura J Allen
Melissa Lee
Pablo J Cabrera
P2860
P304
P356
10.1021/JA501906X
P407
P50
P577
2014-04-04T00:00:00Z