From understanding to prediction: gold- and platinum-based π-acid catalysis for target oriented synthesis.
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Synthesis, structure and catalytic activity of a gold(I) complex containing 1,2-bis(diphenylphosphino)benzene monoxide.Total Synthesis, Stereochemical Revision, and Biological Reassessment of Mandelalide A: Chemical Mimicry of Intrafamily Relationships.Asymmetric gold-catalyzed lactonizations in water at room temperatureGold-catalyzed 1,3-transposition of ynones.Anatomy of gold catalysts: facts and mythsSynthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines.Gold-catalyzed three-component spirocyclization: a one-pot approach to functionalized pyrazolidines.Towards a general diastereoselective route to oxabicyclo[3.2.1]octanes via a gold-catalysed cascade reactionWhen gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis.The Cation-π Interaction in Small-Molecule Catalysis.Which Metals are Green for Catalysis? Comparison of the Toxicities of Ni, Cu, Fe, Pd, Pt, Rh, and Au Salts.Rearrangement of a Transient Gold Vinylidene into Gold Carbenes.Recent Developments in Coinage Metal Catalyzed Transformations of Stabilized Vinyldiazo Compounds: Beyond Carbenic Pathways.Gold-Catalyzed Enantioselective Annulations.Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes.Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition.The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation.Gold- or Silver-Catalyzed Syntheses of Pyrones and Pyridine Derivatives: Mechanistic and Synthetic Aspects.Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture.Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization.An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.Pyridylidene ligand facilitates gold-catalyzed oxidative C-H arylation of heterocycles.α,β-Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5-Alkoxy Migration of 1,6-Enynes: Mechanisms and Applications.Gold carbene or carbenoid: is there a difference?Ligand-controlled gold-catalyzed cycloisomerization of 1,n-enyne esters toward synthesis of dihydronaphthalene.Catalytic σ-activation of carbon-carbon triple bonds: reactions of propargylic alcohols and alkynes.Silver-free activation of ligated gold(I) chlorides: the use of [Me3NB12Cl11]- as a weakly coordinating anion in homogeneous gold catalysis.Merging gold catalysis, organocatalytic oxidation, and Lewis acid catalysis for chemodivergent synthesis of functionalized oxazoles from N-propargylamides.Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction.Metal-Catalyzed Cyclization Reactions of 2,3,4-Trien-1-ols: A Joint Experimental-Computational Study.Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon-carbon bonds.Divergent synthesis from reactions of 2-trifluoromethyl-1,3-conjugated enynes with N-acetylated 2-aminomalonates.Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters.Enantioselective Tandem Cyclization of Alkyne-Tethered Indoles Using Cooperative Silver(I)/Chiral Phosphoric Acid Catalysis.A 11-Steps Total Synthesis of Magellanine through a Gold(I)-Catalyzed Dehydro Diels-Alder Reaction.Polyunsaturated C-Glycosidic 4-Hydroxy-2-pyrone Derivatives: Total Synthesis Shows that Putative Orevactaene Is Likely Identical with Epipyrone A.The synthesis of cycloalka[b]furans via an Au(i)-catalyzed tandem reaction of 3-yne-1,2-diols.Gold-catalysed cross-coupling between aryldiazonium salts and arylboronic acids: probing the usefulness of photoredox conditions.
P2860
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P2860
From understanding to prediction: gold- and platinum-based π-acid catalysis for target oriented synthesis.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh
2013年學術文章
@zh-hant
name
From understanding to predicti ...... for target oriented synthesis.
@en
From understanding to predicti ...... for target oriented synthesis.
@nl
type
label
From understanding to predicti ...... for target oriented synthesis.
@en
From understanding to predicti ...... for target oriented synthesis.
@nl
prefLabel
From understanding to predicti ...... for target oriented synthesis.
@en
From understanding to predicti ...... for target oriented synthesis.
@nl
P356
P1476
From understanding to predicti ...... for target oriented synthesis.
@en
P304
P356
10.1021/AR4001789
P407
P577
2013-11-26T00:00:00Z