Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
about
Diels-Alder cycloaddition as a new approach toward stable PC(sp3)P-metalated compounds.Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines.Carbon-heteroatom bond formation catalysed by organometallic complexesActivation and coordination of ammonia at [Cp*Ir(H)2]: NMR and matrix isolation studies.Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I) Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base Coordination.New ligand platforms featuring boron-rich clusters as organomimetic substituents(.)Neutral tridentate PNP ligands and their hybrid analogues: versatile non-innocent scaffolds for homogeneous catalysis.Mechanistic aspects and elementary steps of N-H bond activation of ammonia and C-N coupling induced by gas-phase ions: a combined experimental/computational exercise.Silicon-doping in carbon nanotubes: formation energies, electronic structures, and chemical reactivity.Cationic mono and dicarbonyl pincer complexes of rhodium and iridium to assess the donor properties of PCcarbeneP ligands.Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes.On the Ambiphilic Reactivity of Geometrically Constrained Phosphorus(III) and Arsenic(III) Compounds: Insights into Their Interaction with Ionic Substrates.Homogeneous catalytic hydroamination of alkynes and allenes with ammonia.E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.Activation of gaseous PH3 with low coordinate diaryltetrylene compounds.Activation of Si-H, B-H, and P-H bonds at a single nonmetal center.Analysis of potential molecular catalysts for the hydroamination of ethylene with ammonia: a DFT study with [Ir(PCP)] and [Ir(PSiP)] complexes.Ammonia activation at a metal.Cationic and neutral Ni(II) complexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species.Reactivity of the parent amido complexes of iridium with olefins: C-NH2 bond formation versus C-H activation.Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium.Synthesis and characterization of a family of POCOP pincer complexes with nickel: reactivity towards CO2 and phenylacetylene.C-NH2 bond formation mediated by iridium complexes.P-H activation of secondary phosphanes on a parent amido diiridium complex.A Sterically Constrained Tricyclic PC3 Phosphine: Coordination Behavior and Insertion of Chalcogen Atoms into P-C Bonds.Reactions involving some gas molecules through sequestration on Al12 Be cluster: An electron density based study.The synthesis and efficient one-pot catalytic "self-breeding" of asymmetrical NC(sp(3))E-hybridised pincer complexes.Understanding the reaction mechanism of the oxidative addition of ammonia by (PXP)Ir(i) complexes: the role of the X group.Coordination-induced weakening of ammonia, water, and hydrazine X-H bonds in a molybdenum complex.A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules.N-H bond cleavage of ammonia on graphene-like B36 borophene: DFT studies.Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.Thermal ammonia activation by cationic transition-metal hydrides of the first row--small but mighty.Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3.Thermal activation of N-H bonds by transition-metal oxide cations: does a hierarchy exist in the first row?Mechanistic insights into small molecule activation induced by ligand cooperativity in PCcarbeneP nickel pincer complexes: a quantum chemistry study.N-H bond activation by palladium(II) and copper(I) complexes featuring a reactive bidentate PN-ligand.Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium.A new PC(sp(3))P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes.
P2860
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P2860
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh
2005年學術文章
@zh-hant
name
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
@en
type
label
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
@en
prefLabel
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
@en
P356
P1433
P1476
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
@en
P2093
P304
P356
10.1126/SCIENCE.1109389
P407
P577
2005-02-01T00:00:00Z