Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2).
about
Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalystsStructurally Characterized Cationic Silver(I) and Ruthenium(II)carbene complexes of 1,2,3-Triazol-5-ylidenesExperimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).Stable cyclic carbenes and related species beyond diaminocarbenes.Normal-to-Abnormal NHC Rearrangement of Al(III) , Ga(III) , and In(III) Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation.Phosphorescent Platinum(II) Complexes with Mesoionic 1H-1,2,3-Triazolylidene Ligands.A Brief Survey of our Contribution to Stable Carbene Chemistry.Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.Rare-Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic OlefinSynthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.Insights into the carbene-initiated aggregation of [Fe(cot)(2)].Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(II) complexes and their catalytic properties.Unexpected oxidative C-C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes.Designing the "search pathway" in the development of a new class of highly efficient stereoselective hydrosilylation catalysts.Heteroleptic rhodium NHC complexes with pyridine-derived ligands: synthetic accessibility and reactivity towards oxygen.Stability and electronic properties of imidazole-based mesoionic carbenes.A Capped Octahedral MHC6 Compound of a Platinum Group Metal.Fischer carbene complexes remain favourite targets, and vehicles for new discoveries.Imidazol-2-and-4-ylidene by decarboxylation. Studies on the cross-conjugated mesomeric betaine-alkaloid norzooanemonine and its pseudo-cross-conjugated isomer.Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene.A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects.A comparative study on the N-heterocyclic carbene adducts of Ih-C60, D5h-C70 and Sc3N@Ih-C80.1,3,2-Diazaborole-derived carbene complexes of boron.Coordination Behavior of a Planar Chiral Cyclic (Amino)(Ferrocenyl)Carbene Ligand in Iridium Complexes.Copper(I) complexes of mesoionic carbene: structural characterization and catalytic hydrosilylation reactions.Formation of CC-type palladacycles with assistance from an apparently innocent NH(CO) functional group.Structural and theoretical investigation of 2-iminoimidazolines--carbene analogues of iminophosphoranes.Ru-Ag and Ru-Au dicarbene complexes from an abnormal carbene ruthenium system.Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights† †Dedicated to the memory of Paul von R. Schleyer. ‡ ‡Electronic supplementary information (ESI) available: CIF files giCounter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2Smooth C(alkyl)–H bond activation in rhodium complexes comprising abnormal carbene ligandsNeutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene HydrogenationStrong electron-donating metalla-N-heterocyclic carbenes
P2860
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P2860
Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2).
description
2002 nî lūn-bûn
@nan
2002年の論文
@ja
2002年論文
@yue
2002年論文
@zh-hant
2002年論文
@zh-hk
2002年論文
@zh-mo
2002年論文
@zh-tw
2002年论文
@wuu
2002年论文
@zh
2002年论文
@zh-cn
name
Abnormal ligand binding and re ...... salts with IrH(5)(PPh(3))(2).
@en
type
label
Abnormal ligand binding and re ...... salts with IrH(5)(PPh(3))(2).
@en
prefLabel
Abnormal ligand binding and re ...... salts with IrH(5)(PPh(3))(2).
@en
P2093
P356
P1476
Abnormal ligand binding and re ...... m salts with IrH(5)(PPh(3))(2)
@en
P2093
Anes Kovacevic
Robert H Crabtree
Stephan Gründemann
P304
10473-10481
P356
10.1021/JA026735G
P407
P577
2002-09-01T00:00:00Z