Nine-step enantioselective total synthesis of (-)-vincorine.
about
The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Atom economical, one-pot, three-reaction cascade to novel tricyclic 2,4-dihydro-1H-benzo[f]isochromenesEnantioselective Total Syntheses of Akuammiline Alkaloids (+)-Strictamine, (-)-2(S)-Cathafoline, and (-)-Aspidophylline A.Total synthesis of the akuammiline alkaloid picrinine.Cascade reactions: a driving force in akuammiline alkaloid total synthesis.Alkaloid synthesis using chiral secondary amine organocatalysts.Acylammonium salts as dienophiles in Diels-Alder/lactonization organocascades.Arylation of diazoesters by a transient N-H insertion organocascade.Palladium(0)-catalyzed intramolecular dearomative arylation of pyrroles.Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles.Total Synthesis of (±)-Corymine.Indium(III)-catalyzed Aza-Conia-Ene Reaction for the Synthesis of Indolizines.Synthesis of C3-Methyl-Substituted Pyrroloindolines and Furoindolines via Cascade Dearomatization of Indole Derivatives with Methyl Iodide.Et3B-mediated two- and three-component coupling reactions via radical decarbonylation of α-alkoxyacyl tellurides: single-step construction of densely oxygenated carboskeletons.Formal total synthesis of the akuammiline alkaloid (+)-strictamine.Enantioselective Synthesis of Pyrroloindolines via Noncovalent Stabilization of Indole Radical Cations and Applications to the Synthesis of Alkaloid Natural Products.Asymmetric Synthesis of Furo[3,4-b]indoles by Catalytic [3+2] Cycloaddition of Indoles with Epoxides.Asymmetric dearomatization of indoles through a Michael/Friedel-Crafts-type cascade to construct polycyclic spiroindolines.Efficient synthesis of carbazolespirooxindole skeletons via asymmetric Diels-Alder reaction of 3-vinylindoles and methyleneindolinones.Total Synthesis of (+)-Minfiensine: Construction of the Tetracyclic Core Structure by an Asymmetric Cascade Cyclization.Iridium-Catalyzed Enantioselective Indole Cyclization: Application to the Total Synthesis and Absolute Stereochemical Assignment of (-)-Aspidophylline A.Access to Hexahydrocarbazoles: The Thorpe-Ingold Effects of the Ligand on Enantioselectivity.Palladium-catalyzed dearomative cyclization by a norbornene-mediated sequence: a route to spiroindolenine derivatives.An Indoxyl-Based Strategy for the Synthesis of Indolines and Indolenines.Copper(I)-Catalyzed Asymmetric Dearomatization of Indole Acetamides with 3-Indolylphenyliodonium Salts.Total Synthesis of (±)-Strictamine.Enantioselective Total Syntheses of Methanoquinolizidine-Containing Akuammiline Alkaloids and Related Studies.Pardon the Interruption: A Modification of Fischer's Venerable Reaction for the Synthesis of Heterocycles and Natural Products.A facile one-pot method to synthesise 2-alkylated indole and 2,2′-bis(indolyl)methane derivatives using ketones as electrophiles and their anion sensing abilitySimple indole alkaloids and those with a nonrearranged monoterpenoid unit
P2860
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P2860
Nine-step enantioselective total synthesis of (-)-vincorine.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Nine-step enantioselective total synthesis of (-)-vincorine.
@en
type
label
Nine-step enantioselective total synthesis of (-)-vincorine.
@en
prefLabel
Nine-step enantioselective total synthesis of (-)-vincorine.
@en
P2860
P356
P1476
Nine-step enantioselective total synthesis of (-)-vincorine.
@en
P2093
Benjamin D Horning
David W C MacMillan
P2860
P304
P356
10.1021/JA402933S
P407
P577
2013-04-19T00:00:00Z