A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids.
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Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacyclePalladium-catalyzed borylation of aryl and heteroaryl halides utilizing tetrakis(dimethylamino)diboron: one step greener.Mild Pd-catalyzed aminocarbonylation of (hetero)aryl bromides with a palladacycle precatalystRoom temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling.Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides.Stereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides.Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions.Application of a catalytic asymmetric Povarov reaction using chiral ureas to the synthesis of a tetrahydroquinoline library.Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions.Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric SynthesisCross-coupling of mesylated phenol derivatives with potassium alkoxymethyltrifluoroborates.Completely N1-selective palladium-catalyzed arylation of unsymmetric imidazoles: application to the synthesis of nilotinibSynthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate.Total Synthesis of (-)-Nodulisporic Acid D.Photostabilizing Efficiency of PVC in the Presence of Schiff Bases as Photostabilizers.A modified procedure for the palladium catalyzed borylation/Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides utilizing bis-boronic acid.Concise total synthesis and stereochemical revision of (+)-naseseazines A and B: regioselective arylative dimerization of diketopiperazine alkaloidsPalladium-catalyzed β-(hetero)arylation of α,β-unsaturated valerolactams.Rapid and efficient access to secondary arylmethylamines.Mechanistic Investigation of Catalyst-Transfer Suzuki-Miyaura Condensation Polymerization of Thiophene-Pyridine Biaryl Monomers with the Aid of Model Reactions.Diastereoselective Oxidative C-N/C-O and C-N/C-N Bond Formation Tandems Initiated by Visible Light: Synthesis of Fused N-Arylindolines.Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.Direct C7 Functionalization of Tryptophan. Synthesis of Methyl (S)-2-((tert-Butoxycarbonyl)amino)-3-(7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indol-3-yl)propanoate.Pd-catalyzed aldehyde to ester conversion: a hydrogen transfer approach.Palladium-catalyzed α-arylation of 2-chloroacetates and 2-chloroacetamidesNickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst.Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts.Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.Pd-catalyzed cross-coupling of potassium alkenyltrifluoroborates with 2-chloroacetates and 2-chloroacetamides.Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acidsLigand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halidesSuzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactionsSuzuki-Miyaura cross-coupling optimization enabled by automated feedback.A Divalent Protecting Group for Benzoxaboroles.Palladium-Catalyzed α-Arylation of Methyl Sulfonamides with Aryl Chlorides.Total synthesis, stereochemical assignment, and biological activity of all known (-)-trigonoliimines.Synthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl CompoundsA General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.
P2860
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P2860
A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
A new palladium precatalyst al ...... nd 2-heteroaryl boronic acids.
@en
type
label
A new palladium precatalyst al ...... nd 2-heteroaryl boronic acids.
@en
prefLabel
A new palladium precatalyst al ...... nd 2-heteroaryl boronic acids.
@en
P2093
P2860
P356
P1476
A new palladium precatalyst al ...... nd 2-heteroaryl boronic acids.
@en
P2093
Stephen L Buchwald
Tom Kinzel
Yong Zhang
P2860
P304
14073-14075
P356
10.1021/JA1073799
P407
P577
2010-10-01T00:00:00Z