Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
about
Studies on C20-diterpenoid alkaloids: synthesis of the hetidine framework and its application to the synthesis of dihydronavirine and the atisine skeletonCarbamoyl radical-mediated synthesis and semipinacol rearrangement of β-lactam diols.Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systemsThe chemistry of isoindole natural products.Terpenoid-Alkaloids: Their Biosynthetic Twist of Fate and Total SynthesisAchieving regio- and enantioselectivity of P450-catalyzed oxidative CH activation of small functionalized molecules by structure-guided directed evolution.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks.Syntheses of Denudatine Diterpenoid Alkaloids: Cochlearenine, N-Ethyl-1α-hydroxy-17-veratroyldictyzine, and Paniculamine.Dipolar addition to cyclic vinyl sulfones leading to dual conformation tricycles.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesAcyclic quaternary centers from asymmetric conjugate addition of alkylzirconium reagents to linear trisubstituted enones.A unified approach to ent-atisane diterpenes and related alkaloids: synthesis of (-)-methyl atisenoate, (-)-isoatisine, and the hetidine skeleton.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Gallium(III)-catalyzed cycloisomerization approach to the diterpenoid alkaloids: construction of the core structure for the hetidines and hetisines.Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis.Stereoselective Total Synthesis of Hetisine-type C20 -Diterpenoid Alkaloids: Spirasine IV and XI.Catalytic diastereo- and enantioselective additions of versatile allyl groups to N-H ketimines.Synthesis of Atisine, Ajaconine, Denudatine, and Hetidine Diterpenoid Alkaloids by a Bioinspired Approach.Versatile Homoallylic Boronates by Chemo-, SN 2'-, Diastereo- and Enantioselective Catalytic Sequence of Cu-H Addition to Vinyl-B(pin)/Allylic Substitution.(4+3) Cycloaddition Reactions of N-Alkyl Oxidopyridinium Ions.
P2860
Q33998792-B03CB426-13AF-4C37-B17C-8D99991222EAQ35061109-D8B93399-5BDC-4CAE-BCA0-78963C1AB8F3Q36651992-EF272FF9-65DD-40AC-B3DF-A3AA53124DB9Q37279822-29C6638F-290F-4522-9107-4733C2186CCEQ38553413-4BF922BF-1F88-442A-9A12-C36F27C98725Q39600354-F9C90524-9C15-4634-9AE3-47B9DDF3FFD6Q40435109-E4492948-DA21-4E09-B6AC-B42AA322A854Q41478233-8DF5A4DC-C20B-43A8-A47A-38910C34E7BBQ41552162-452398E1-F1BA-4C38-BDE2-7D4D29EE8761Q41998828-674646B8-AEB2-4FA2-A064-7781F9A61ACEQ42007847-E430AEFD-EA41-48B3-9CB6-FDA86653B3A2Q42029518-48424F17-C439-4B66-924F-F82ABEF577FEQ42038638-206966BF-56AE-40D8-B04B-4995896A789BQ42114279-15EEF42F-165D-4EFB-B010-EA079509FC85Q42212219-4265C8AD-44DA-4FC0-A92A-051F9960D04CQ42585326-015D29A3-61CD-44FF-8428-E495584AA1DBQ43196623-EAEC05CB-F283-44E5-93A3-2EC69F46CAF9Q48178519-0407090A-1046-4FE9-854F-B822FAE34589Q48247687-7FE5DB95-3431-4E39-88E6-BF49F40FF9D7Q48930956-F03E3DA4-C9AA-42D8-849C-B26D8791DABCQ49369452-3F26CB85-7875-49A7-BB92-B5900DFA14B7Q50000533-C474EB8C-1F3D-4F20-A436-86BADC3AB3D0
P2860
Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
@en
type
label
Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
@en
prefLabel
Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
@en
P2860
P356
P1476
Asymmetric synthetic access to the hetisine alkaloids: total synthesis of (+)-nominine.
@en
P2093
David Y Gin
Kevin M Peese
P2860
P304
P356
10.1002/CHEM.200701290
P407
P577
2008-01-01T00:00:00Z