A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
about
Palladium-catalyzed regioselective azidation of allylic C-H bonds under atmospheric pressure of dioxygen.Chemo- and regioselective C(sp³)-H arylation of unactivated allylarenes by deprotonative cross-couplingMolecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-CouplingPd(0)-catalyzed sequential C-N bond formation via allylic and aromatic C-H amination of α-methylstyrenes with diaziridinone.If C-H bonds could talk: selective C-H bond oxidationThe emergence of sulfoxides as efficient ligands in transition metal catalysis.Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins.C-H imidation: a distinct perspective of C-N bond formation.Recent advances in reactions of aryl sulfonyl isocyanates.Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition.A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp(3))-H amination.Late-stage deoxyfluorination of alcohols with PhenoFluor.N-Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/Brønsted acid co-catalyzed allylic C-H oxidation.Allylic C-H amination for the preparation of syn-1,3-amino alcohol motifs.Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation.Efficient domino approaches to multifunctionalized fused pyrroles and dibenzo[b,e][1,4]diazepin-1-ones.Synthesis of complex allylic esters via C-H oxidation vs C-C bond formation.Diversification of a β-Lactam Pharmacophore via Allylic C-H Amination: Accelerating Effect of Lewis Acid Co-Catalyst.A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins.Mild copper-mediated direct oxidative cross-coupling of 1,3,4-oxadiazoles with polyfluoroarenes by using dioxygen as oxidant.Iodine-Catalyzed Decarboxylative Amidation of β,γ-Unsaturated Carboxylic Acids with Chloramine Salts Leading to Allylic Amides.Dormant versus evolving aminopalladated intermediates: toward a unified mechanistic scenario in Pd(II)-catalyzed aminations.Access to Chiral Hydropyrimidines through Palladium-Catalyzed Asymmetric Allylic C-H Amination.Copper-catalyzed remote (δ) C(sp3)-H bond amination: a practical strategy to construct pyrrolidine derivatives.Visible-Light-Induced Direct Oxidative C-H Amidation of Heteroarenes with Sulfonamides.Regioselective Intermolecular Allylic C-H Amination of Disubstituted Olefins via Rhodium/π-Allyl Intermediates.Coordination strategy-induced selective C-H amination of 8-aminoquinolines.Palladium-catalyzed aerobic oxidative double allylic C-H oxygenation of alkenes: a novel and straightforward route to α,β-unsaturated esters.TEMPO-mediated allylic C-H amination with hydrazones.An Efficient Amide-Aldehyde-Alkene Condensation: Synthesis for the N-Allyl Amides.Palladium-catalyzed aerobic oxidative allylic C-H arylation of alkenes with polyfluorobenzenes.Iminoxyl Radical-Based Strategy for Intermolecular CO Bond Formation: Cross-Dehydrogenative Coupling of 1,3-Dicarbonyl Compounds with OximesFormal C–H amination of cyclopropenes
P2860
Q33461327-AA14121A-FD07-4C21-848F-EC8E8583F4EAQ33684516-198A33CE-9BA2-4E11-8835-C59A789ED5C6Q34208102-3E879901-BAF4-4104-8A0A-939C3CD680A9Q36242189-AE54D5CC-C04C-4F02-A79D-037D74CC1886Q37396046-0BE3551B-B079-48FD-A107-DF50B2EC5193Q37853955-792BEB6B-C3F3-404E-99B4-7E53ABE668BBQ38467074-F01D9300-E798-40D5-8A03-22B863714111Q38583737-01A92D1C-858B-423B-A779-E945074F5BA9Q39091758-A0CFD829-D9D6-438E-9104-3C595D26A395Q39106048-696BB977-E769-4EA2-9D99-CFCB51E8BB48Q40174187-D43C975C-FDE0-4468-B1DC-E8587FD836BDQ40357253-D4D66ED0-B575-4B15-9594-FAB058A95C9AQ41154032-CBA1686C-EA55-48B7-888F-5411B2404BA4Q41893006-47C7A923-14D8-4916-A337-29BC615E7DD8Q41981595-ED4555F3-DACF-4916-9A64-E54650A8C007Q42008495-BEB428DE-81FB-4722-A816-6915DF929514Q42145721-7101CF4E-2AE1-46B2-8DAA-AFA4E055F0AAQ42211858-7007D632-DE58-4A8C-A241-F1E34829CA28Q42645268-47177C32-F54D-4C05-9327-EE9299F3F7ABQ42723148-7C6909B5-C780-4E56-9BF0-6C5277BA0699Q42741143-DE2CFB3D-1388-4B0A-97C4-7FD54773778AQ42775390-0D6698AB-CABD-4842-AF00-6C1712BA3F64Q45152068-CFAC6F5A-3F1D-4E1D-9E33-C927E2C2EF41Q46650055-61973CE4-71DF-4827-BB23-853E7A8E2D8AQ46949005-BC2276CD-4070-4489-9083-04A479631B92Q47417152-00B8787D-827F-43FD-98D6-2363C5C790F3Q48160580-C9E83C20-4DB0-4A9C-9275-7CB745BF905DQ48293278-49E9ECEA-3E45-4AF4-A6E8-53CD2D7B3C23Q48340941-539895D5-29B9-4349-AD83-2BDDA89B6BA4Q48773067-645641E6-A2EE-4614-8B9D-3787EDBB05E4Q50277344-6093465B-193B-44A7-82DE-E084BCA0D72AQ51083868-7A57FDED-F9BF-44D8-8B1C-AB63EE02F733Q51548230-59AF8C76-3BDD-4FD0-B0A2-9E006400FDD3Q53540773-943504A8-B2DA-43DE-96F2-935F458D5BBBQ57585796-09324304-E78B-490C-BEDF-AA4077B49A64Q59255941-1FB899C7-ADE1-4606-A512-8DF6B8BA1BA8
P2860
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
@en
type
label
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
@en
prefLabel
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
@en
P2093
P2860
P356
P1476
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
@en
P2093
Anthony R Mazzotti
M Christina White
Sean A Reed
P2860
P304
11701-11706
P356
10.1021/JA903939K
P407
P577
2009-08-01T00:00:00Z