Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
about
Dinitrogen binding and cleavage by multinuclear iron complexesNitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexesCharacterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting StateCatalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET.Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride LigandsStructural characterization of CO-inhibited Mo-nitrogenase by combined application of nuclear resonance vibrational spectroscopy, extended X-ray absorption fine structure, and density functional theory: new insights into the effects of CO binding anAlkali metal control over N-N cleavage in iron complexes.Binding of dinitrogen to an iron-sulfur-carbon siteAlkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes.Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia.The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry.Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.Nitrogenase Cofactor: Inspiration for Model Chemistry.An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction.Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.Evaluating molecular cobalt complexes for the conversion of N2 to NH3Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation.Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixationElectronic nature of zwitterionic alkali metal methanides, silanides and germanides - a combined experimental and computational approach.Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand.A 10(6)-fold enhancement in N2-binding affinity of an Fe2(μ-H)2 core upon reduction to a mixed-valence Fe(II)Fe(I) state.Cadmium Compounds with an [N3C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species.N2 -to-NH3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis.Synthetic Analogues of Nitrogenase Metallocofactors: Challenges and Developments.Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation.Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes.Cobalt-catalyzed transformation of molecular dinitrogen into silylamine under ambient reaction conditions.Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor.Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.Catalytic Conversion of Dinitrogen into Ammonia under Ambient Reaction Conditions by Using Proton Source from Water.Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.Selective nitrogen capture by porous hybrid materials containing accessible transition metal ion sites.Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis.Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands.Synthesis and reactivity of thiolate-bridged multi-iron complexes supported by cyclic (alkyl)(amino)carbene.Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes.High-Spin Iron(I) and Iron(0) Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands.Polymer- and silica-supported iron BPMEN-inspired catalysts for C-H bond functionalization reactions.
P2860
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P2860
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年論文
@yue
2014年論文
@zh-hant
2014年論文
@zh-hk
2014年論文
@zh-mo
2014年論文
@zh-tw
2014年论文
@wuu
2014年论文
@zh
2014年论文
@zh-cn
name
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
@en
type
label
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
@en
prefLabel
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
@en
P2860
P356
P1476
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.
@en
P2093
Jonas C Peters
Sidney E Creutz
P2860
P304
P356
10.1021/JA4114962
P407
P577
2014-01-09T00:00:00Z