Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.
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Mononuclear metal-O2 complexes bearing macrocyclic N-tetramethylated cyclam ligandsA Mononuclear Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Metal IonsStructure and reactivity of a mononuclear non-haem iron(III)-peroxo complex.Characterization of a thiolato iron(III) Peroxy dianion complex.Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituentX-ray absorption near-edge spectroscopy in bioinorganic chemistry: Application to M-O2 systemsComparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivitiesSpectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions.Applications of density functional theory to iron-containing molecules of bioinorganic interest.Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites.Mechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases.An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway.Intermediate P* from soluble methane monooxygenase contains a diferrous cluster.Redox Non-Innocence of Nitrosobenzene at Nickel.Analysis of an alternative to the H-atom abstraction mechanism in methane C-H bond activation by nonheme iron(IV)-oxo oxidants.Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.Cross-linking of dicyclotyrosine by the cytochrome P450 enzyme CYP121 from Mycobacterium tuberculosis proceeds through a catalytic shunt pathway.Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species.Demonstration of the heterolytic O-O bond cleavage of putative nonheme iron(II)-OOH(R) complexes for Fenton and enzymatic reactions.A DFT and ONIOM study of C-H hydroxylation catalyzed by nitrobenzene 1,2-dioxygenase.Formation of high-valent iron-oxo species in superoxide reductase: characterization by resonance Raman spectroscopy.Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations.Spectroscopic evidence for the role of a site of the di-iron catalytic center of ferritins in tuning the kinetics of Fe(ii) oxidation.The "innocent" role of Sc(3+) on a non-heme Fe catalyst in an O2 environment.
P2860
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P2860
Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Characterization of a high-spi ...... ersion to an Fe(IV)═O complex.
@en
type
label
Characterization of a high-spi ...... ersion to an Fe(IV)═O complex.
@en
prefLabel
Characterization of a high-spi ...... ersion to an Fe(IV)═O complex.
@en
P2093
P2860
P356
P1476
Characterization of a high-spi ...... ersion to an Fe(IV)═O complex.
@en
P2093
Eckard Münck
Katherine M Van Heuvelen
Katlyn K Meier
Lawrence Que
Matthew A Cranswick
Mrinmoy Chakrabarti
P2860
P304
P356
10.1021/JA111742Z
P407
P577
2011-04-25T00:00:00Z