Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation. - Wikidata - awgldk - TriplyDB

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

http://www.wikidata.org/entity/Q42084579

about

Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis Metal-free, cooperative asymmetric organophotoredox catalysis with visible light.Direct and enantioselective {alpha}-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis Mechanistic complexity in organo-SOMO activation Diasteroselective preparation of cyclopropanols using methylene bis(iodozinc).Chiral calcium VAPOL phosphate mediated asymmetric chlorination and Michael reactions of 3-substituted oxindoles.Enantioselective dichlorination of allylic alcohols.Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysis Sultones and Sultines via a Julia-Kocienski Reaction of Epoxides α-Haloaldehydes: versatile building blocks for natural product synthesis.Rapid, one-pot synthesis of β-siloxy-α-haloaldehydes.N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids.A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis.Enantioselective polyene cyclization via organo-SOMO catalysis.Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity.Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids.Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products.The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction Organocatalytic stereoselective alpha-alkylation of aldehydes with stable carbocations.Total synthesis and structural revision of laurefurenynes A and B.Organocatalytic asymmetric epoxidation and tandem epoxidation/Passerini reaction under eco-friendly reaction conditions.Total Synthesis and Configurational Assignment of Ascospiroketal A.Enantioselective synthesis of δ-/γ-alkoxy-β-hydroxy-α-alkyl-substituted Weinreb amides via DKR-ATH: application to the synthesis of advanced intermediate of (-)-brevisamide.Chlorine, an atom economical auxiliary for asymmetric aldol reactions.

P2860

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P2860

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

http://www.wikidata.org/entity/Q42084579

description

2009 nî lūn-bûn

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2009年の論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年论文

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2009年论文

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2009年论文

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name

Enantioselective linchpin cata ...... nd terminal epoxide formation.

@en

Enantioselective linchpin cata ...... nd terminal epoxide formation.

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type

label

Enantioselective linchpin cata ...... nd terminal epoxide formation.

@en

Enantioselective linchpin cata ...... nd terminal epoxide formation.

@nl

prefLabel

Enantioselective linchpin cata ...... nd terminal epoxide formation.

@en

Enantioselective linchpin cata ...... nd terminal epoxide formation.

@nl

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Angewandte Chemie International Edition

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Enantioselective linchpin cata ...... and terminal epoxide formation

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David W C MacMillan

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Sean P Brown

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Teresa D Beeson

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P2860

Merging photoredox catalysis with organocatalysis: the direct asymmetric alkylation of aldehydes

Enantioselective organo-cascade catalysis

Direct and enantioselective organocatalytic alpha-chlorination of aldehydes.

Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.

Catalytic asymmetric synthesis of alpha-amino acids.

Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis.

Asymmetric enamine catalysis.

Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes.

Highly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen)Co(III) complexes. Practical synthesis of enantioenriched terminal epoxides and 1,2-diols.

Designing new chiral ketone catalysts. Asymmetric epoxidation of cis-olefins and terminal olefins.

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5121-5124

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10.1002/ANIE.200901855

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19526479

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enantioselectivity

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3439133

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