Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).
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Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical IndustryActivation of Dioxygen by a TAML Activator in Reverse Micelles: Characterization of an Fe(III)Fe(IV) Dimer and Associated Catalytic ChemistryNi(II)-catalyzed dehydrative alkynylation of unactivated (hetero)aryl C-H bonds using oxygen: a user-friendly approach.Non-Directed Allylic C-H Acetoxylation in the Presence of Lewis Basic Heterocycles.On the mechanism of the palladium bis(NHC) complex catalyzed CH functionalization of propane: experiment and DFT calculations.Copper-catalyzed regioselective synthesis of furan via tandem cycloaddition of ketone with an unsaturated carboxylic acid under air.Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazineAlkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsScalable and sustainable electrochemical allylic C-H oxidation.Selective, Tunable O2 Binding in Cobalt(II)-Triazolate/Pyrazolate Metal-Organic Frameworks.Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process.Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification.Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development.Liquid phase oxidation chemistry in continuous-flow microreactors.Coordination chemistry and applications of versatile 4,5-diazafluorene derivatives.Copper-catalyzed oxidative carbon-heteroatom bond formation: a recent update.The past, present, and future of the Yang reaction.Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond.C-Alkylation by Hydrogen Autotransfer Reactions.Activation of dioxygen by copper metalloproteins and insights from model complexes.Synthesis of imidazo[1,2-a]pyridines: C-H functionalization in the direction of C-S bond formation.Direct C-H arene homocoupling over gold nanoparticles supported on metal oxides.Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants.Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions.Oxidative dehydrogenation of C-C and C-N bonds: A convenient approach to access diverse (dihydro)heteroaromatic compounds.Experimental and computational studies on the C-H amination mechanism of tetrahydrocarbazoles via hydroperoxides.Copper-catalyzed etherification of arene C-H bonds.Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes.Photocatalytic synthesis of dihydrobenzofurans by oxidative [3+2] cycloaddition of phenols.Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands.Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite.Monoselective o-C-H Functionalizations of Mandelic Acid and α-Phenylglycine.Overcoming the limitations of directed C-H functionalizations of heterocycles.Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes.Base metal-catalyzed benzylic oxidation of (aryl)(heteroaryl)methanes with molecular oxygen.Palladium Catalyzed Aryl C-H Amination with O2 via In Situ Formation of Peroxide-Based Oxidant(s) from Dioxane.A cascade coupling strategy for one-pot total synthesis of β-carboline and isoquinoline-containing natural products and derivatives.Propane activation by palladium complexes with chelating bis(NHC) ligands and aerobic cooxidation.Copper-catalyzed ortho-halogenation of protected anilines.Aerobic synthesis of pyrroles and dihydropyrroles from imines: palladium(II)-catalyzed intramolecular C-H dehydrogenative cyclization.
P2860
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P2860
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Overcoming the "oxidant proble ...... ions catalyzed by Pd (and Cu).
@en
Overcoming the "oxidant proble ...... tion reactions catalyzed by Pd
@nl
type
label
Overcoming the "oxidant proble ...... ions catalyzed by Pd (and Cu).
@en
Overcoming the "oxidant proble ...... tion reactions catalyzed by Pd
@nl
prefLabel
Overcoming the "oxidant proble ...... ions catalyzed by Pd (and Cu).
@en
Overcoming the "oxidant proble ...... tion reactions catalyzed by Pd
@nl
P2860
P356
P1476
Overcoming the "oxidant proble ...... ions catalyzed by Pd (and Cu).
@en
P2093
Alison N Campbell
Shannon S Stahl
P2860
P304
P356
10.1021/AR2002045
P407
P577
2012-01-23T00:00:00Z