Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.
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Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence.Stereoselective formation of trisubstituted vinyl boronate esters by the acid-mediated elimination of α-hydroxyboronate esters.Stereospecific pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides.Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides.Configurationally Stable, Enantioenriched Organometallic Nucleophiles in Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach to Asymmetric SynthesisFacile formation of β-hydroxyboronate esters by a Cu-catalyzed diboration/Matteson homologation sequence.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsSynthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl CompoundsCarbonylative Suzuki couplings of aryl bromides with boronic acid derivatives under base-free conditions.Transmetalation in the Suzuki-Miyaura coupling: the fork in the trail.Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions.Mechanistic Insights into Carbonyl-Directed Rhodium-Catalyzed Hydroboration: ab Initio Study of a Cyclic γ,δ-Unsaturated Amide.Enantioselective desymmetrization via carbonyl-directed catalytic asymmetric hydroboration and Suzuki-Miyaura cross-coupling.Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures.Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans.Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds.Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling.Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates.Ligand-Promoted C(sp(3) )-H Olefination en Route to Multi-functionalized Pyrazoles.Retention or inversion in stereospecific nickel-catalyzed cross-coupling of benzylic carbamates with arylboronic esters: control of absolute stereochemistry with an achiral catalyst.Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Enantiospecific, regioselective cross-coupling reactions of secondary allylic boronic esters.Enantioselective Copper-Catalyzed Alkylation of Quinoline N-Oxides with Vinylarenes.A Cu(II)-based strategy for catalytic enantioselective β-borylation of α,β-unsaturated acceptors.ortho-Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific C(sp2 )-C(sp3 ) Cross-Coupling Reactions.Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α-Hydroxyboronates.Direct Access to MIDA Acylboronates through Mild Oxidation of MIDA Vinylboronates.Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling.Enantiospecific sp(2)-sp(3) coupling of secondary and tertiary boronic esters.Practical synthesis of pharmaceutically relevant molecules enriched in sp3 character.Efficient cross-coupling of aryl/alkenyl triflates with acyclic secondary alkylboronic acids.Deboronative cyanation of potassium alkyltrifluoroborates via photoredox catalysis.Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate.Synthesis of chiral heterocycles by ligand-controlled regiodivergent and enantiospecific Suzuki Miyaura cross-coupling.Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides.Copper‐Catalyzed Borylation of Cyclic Sulfamidates: Access to Enantiomerically Pure (β‐and γ‐Aminoalkyl)boronic Esters.Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C-H borylation catalysts.
P2860
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P2860
Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-
@nl
Stereospecific cross-coupling ...... nzyloxy)alkyltrifluoroborates.
@en
type
label
Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-
@nl
Stereospecific cross-coupling ...... nzyloxy)alkyltrifluoroborates.
@en
prefLabel
Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-
@nl
Stereospecific cross-coupling ...... nzyloxy)alkyltrifluoroborates.
@en
P2860
P356
P1476
Stereospecific cross-coupling ...... nzyloxy)alkyltrifluoroborates.
@en
P2093
Steven R Wisniewski
P2860
P304
16856-16868
P356
10.1021/JA307861N
P407
P577
2012-10-01T00:00:00Z