Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway.
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Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes.Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.Direct and enantioselective {alpha}-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis6-Azabicyclo[3.2.1]octanes Via Copper-Catalyzed Enantioselective Alkene Carboamination.Mechanistic complexity in organo-SOMO activationOptimal control of molecular fragmentation with homologous families of photonic reagents and chemical substrates.A systematic investigation of quaternary ammonium ions as asymmetric phase-transfer catalysts. Synthesis of catalyst libraries and evaluation of catalyst activity.Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.Oxidative cyclization reactions: controlling the course of a radical cation-derived reaction with the use of a second nucleophile.Copper-catalyzed intramolecular alkene carboetherification: synthesis of fused-ring and bridged-ring tetrahydrofurans.Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds.Intramolecular anodic olefin coupling reactions: using competition studies to probe the mechanism of oxidative cyclization reactions.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Cyclic enaminones. Part II: applications as versatile intermediates in alkaloid synthesis.Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products.Enantioselective α-arylation of carbonyls via Cu(I)-bisoxazoline catalysis.Progress in Enantioselective Radical Cyclizations.Enantioselective polyene cyclization via organo-SOMO catalysis.Catalytic Radical Domino Reactions in Organic Synthesis.Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins.Cascade radical reaction of substrates with a carbon-carbon triple bond as a radical acceptorEnantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products.The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring ConstructionNovel stereocontrolled syntheses of tashiromine and epitashiromine.Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.Enantioselective α-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis.Organocatalytic stereoselective alpha-alkylation of aldehydes with stable carbocations.Metal-Free Formal Oxidative C-C Coupling by In Situ Generation of an Enolonium Species.Remote enantioselective Friedel-Crafts alkylations of furans through HOMO activation.Direct, enantioselective α-alkylation of aldehydes using simple olefins.Total Synthesis of Ileabethoxazole, Pseudopteroxazole, and seco-Pseudopteroxazole.The versatile roles of ammonium salt catalysts in enantioselective reduction and alkylation of α,β-unsaturated aldehydes: iminium catalysis, enamine catalysis and acid catalysis.A regioselective synthesis of benzopinacolones through aerobic dehydrogenative α-arylation of the tertiary sp3 C-H bond of 1,1-diphenylketones with aromatic and heteroaromatic compounds.Asymmetric Bio- and Organocatalytic Cascade Reaction - Laccase and Secondary Amine-Catalyzed α-Arylation of AldehydesVisible Light Photoredox Catalyzed Cascade Cyclizations of α-Bromochalcones or α-Bromocinnamates with Heteroarenes
P2860
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P2860
Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@en
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@nl
type
label
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@en
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@nl
prefLabel
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@en
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@nl
P2093
P2860
P356
P1476
Enantioselective alpha-arylati ...... ased on an open-shell pathway.
@en
P2093
Brian N Laforteza
David W C MacMillan
Jay C Conrad
Jongrock Kong
P2860
P304
11640-11641
P356
10.1021/JA9026902
P407
P577
2009-08-01T00:00:00Z