An efficient organocatalytic method for constructing biaryls through aromatic C-H activation.
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Ascorbic Acid as an Initiator for the Direct CH Arylation of (Hetero)arenes with Anilines Nitrosated In SituVertically π-expanded imidazo[1,2-a]pyridine: the missing link of the puzzle.General method for functionalized polyaryl synthesis via aryne intermediates.Base-mediated intermolecular sp2 C-H bond arylation via benzyne intermediates.Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides.Organocatalytic C-H activation reactions.A radical process towards the development of transition-metal-free aromatic carbon-carbon bond-forming reactions.The electron is a catalyst.Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization.Functionalization of C-H Bonds by Photoredox Catalysis.Discovery and development of organic super-electron-donors.Mechanistic Study of a Photocatalyzed C-S Bond Formation Involving Alkyl/Aryl Thiosulfate.Nickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides.Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species.Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution.Cross coupling: When is free really free?Transition-metal-free alkynylation of aryl chlorides.A cascade coupling strategy for one-pot total synthesis of β-carboline and isoquinoline-containing natural products and derivatives.Trifluoromethanesulfonic acid catalyzed synergetic oxidative/[3+2] cyclization of quinones with olefins.Chlorine-radical-mediated photocatalytic activation of C-H bonds with visible light.Synthesis of benzimidazoles by potassium tert-butoxide-promoted intermolecular cyclization reaction of 2-iodoanilines with nitriles.Tethering for selective synthesis of 2,2'-biphenols: the acetal method.A new face of phenalenyl-based radicals in the transition metal-free C-H arylation of heteroarenes at room temperature: trapping the radical initiator via C-C σ-bond formation.Effect of solvent on radical cyclisation pathways: SRN1 vs. aryl-aryl bond forming mechanisms.Solventless oxidative coupling of amines to imines by using transition-metal-free metal-organic frameworks.Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane.Nickel-Mediated Synthesis of Isoindolinones at Room Temperature.Direct arylation of inactivated benzene with aryl acyl peroxides toward biaryls.Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n -o-Carboranes (n=1,2) and o-Carborane-Fused Cyclics.Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).t-BuONa-mediated direct C-H halogenation of electron-deficient (hetero)arenes.Transition-metal-free Chemoselective Oxidative C-C Coupling of the sp3 C-H Bond of Oxindoles with Arenes and Addition to Alkene: Synthesis of 3-Aryl Oxindoles, and Benzofuro- and Indoloindoles.Formaldehyde-Extruding Homolytic Aromatic Substitution via C→O Transposition: Selective 'Traceless-Linker' access to Congested Biaryl Bonds.Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters.A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes.Hydroxyl directed C-arylation: synthesis of 3-hydroxyflavones and 2-phenyl-3-hydroxy pyran-4-ones under transition-metal free conditions.Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions.A transition-metal-free fast track to flavones and 3-arylcoumarins.Metal-Free, room-temperature, radical alkoxycarbonylation of aryldiazonium salts through visible-light photoredox catalysis.
P2860
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P2860
An efficient organocatalytic method for constructing biaryls through aromatic C-H activation.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
An efficient organocatalytic m ...... rough aromatic C-H activation.
@en
An efficient organocatalytic m ...... rough aromatic C-H activation.
@nl
type
label
An efficient organocatalytic m ...... rough aromatic C-H activation.
@en
An efficient organocatalytic m ...... rough aromatic C-H activation.
@nl
prefLabel
An efficient organocatalytic m ...... rough aromatic C-H activation.
@en
An efficient organocatalytic m ...... rough aromatic C-H activation.
@nl
P2093
P356
P1433
P1476
An efficient organocatalytic m ...... rough aromatic C-H activation.
@en
P2093
Chang-Liang Sun
Shu-Fang Zheng
Xing-Yu Lu
Zhang-Jie Shi
P2888
P304
P356
10.1038/NCHEM.862
P577
2010-10-03T00:00:00Z