Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction.
about
Catalytic enantioselective C-H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbonTotal Synthesis, Stereochemical Revision, and Biological Reassessment of Mandelalide A: Chemical Mimicry of Intrafamily Relationships.Enantioselective Alcohol C-H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis.Highly stereoselective synthesis of anti,anti-dipropionate stereotriads: a solution to the long-standing problem of challenging mismatched double asymmetric crotylboration reactionsAdvances in the synthesis of glycosidic macrolides: clavosolides A-D and cyanolide A.Enantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadieneDiastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation.Chemical synthesis of the cardiotonic steroid glycosides and related natural products.Polyketide construction via hydrohydroxyalkylation and related alcohol C-H functionalizations: reinventing the chemistry of carbonyl addition.Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.Total synthesis of 6-deoxyerythronolide B via C-C bond-forming transfer hydrogenationRuthenium-catalyzed C-C coupling of fluorinated alcohols with allenes: dehydrogenation at the energetic limit of β-hydride elimination.Total Synthesis of Cryptocaryol A by Enantioselective Iridium-Catalyzed Alcohol C-H Allylation.Stereoselective one-pot synthesis of polypropionates.Total synthesis of cyanolide A in the absence of protecting groups, chiral auxiliaries, or premetalated carbon nucleophiles.Total synthesis of (+)-trienomycins A and F via C-C bond-forming hydrogenation and transfer hydrogenation.Ruthenium(0) Catalyzed Endiyne-α-Ketol [4 + 2] Cycloaddition: Convergent Assembly of Type II Polyketide Substructures via C-C Bond Forming Transfer HydrogenationDirect Generation of Triketide Stereopolyads via Merged Redox-Construction Events: Total Synthesis of (+)-Zincophorin Methyl Ester.Redox-triggered C-C coupling of alcohols and vinyl epoxides: diastereo- and enantioselective formation of all-carbon quaternary centers via tert-(hydroxy)-prenylation.Rapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades.Chiral-anion-dependent inversion of diastereo- and enantioselectivity in carbonyl crotylation via ruthenium-catalyzed butadiene hydrohydroxyalkylation.Ruthenium-BINAP Catalyzed Alcohol C-H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation.Formal Synthesis of Premisakinolide A and C(19)-C(32) of Swinholide A via Site-Selective C-H Allylation and Crotylation of Unprotected DiolsTotal Synthesis of Swinholide A: An Exposition in Hydrogen-Mediated C-C Bond FormationRuthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls.Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis.Diastereoselective Mannich reactions of pseudo-C2-symmetric glutarimide with activated imines.Leptolyngbyolides, Cytotoxic Macrolides from the Marine Cyanobacterium Leptolyngbya sp.: Isolation, Biological Activity, and Catalytic Asymmetric Total Synthesis.Catalytic nucleophilic 'umpoled' π-allyl reagents.Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functional syn-1,3-Diol Derivatives.Direct, Mild, and General n-Bu4NBr-Catalyzed Aldehyde Allylsilylation with Allyl Chlorides.Highly diastereoselective hydrosilylations of allylic alcohols.Asymmetric Allylation of Glycidols Mediated by Allyl Acetate via Iridium-Catalyzed Hydrogen Transfer.
P2860
Q26849589-6A985959-FD50-4694-B959-91127788420BQ33360970-F5EF03A7-DAFA-44E0-B7B7-FC1E929429C8Q34523499-33D3F663-4485-41F5-8B5A-125FA24BE537Q35796016-FD132FDA-21E9-427B-AAE4-CBB0DC9F78EAQ36156057-C572C6C8-5749-449D-B17C-4A32FF1AF80FQ36226256-11FB7359-25B9-4A99-A716-6C4666B066BAQ36233558-A7EA6981-5A3F-45D9-ABA4-2886B0C7658EQ37987052-38ECC7F8-A38F-4F59-9FFB-8EBE1F3E9D4AQ38186988-BC15B651-065D-47F9-8BD6-2ECE461F136DQ38632330-F6D0DF09-846D-42B8-BAB6-516629C66B25Q38844938-82F0440A-A23B-4A66-BA48-B38E5B4C3900Q39372722-4BB29045-5596-424D-8DF0-C55B9D5B8939Q39837642-B7F0274B-C4F7-4B75-846D-C9036A781304Q39850599-DB349AD1-CB40-436E-9806-7D14EF5430C0Q40285034-79DA9997-64BA-4D31-B827-91DD9643AC2BQ41686677-6E4F4CD6-DFF8-483C-A006-364AAA2164D4Q41827256-484A4F65-DD77-407C-B793-87B47E007B4FQ41844095-3F74DBA5-4A71-433F-96C7-B1668B9A2275Q41878135-693ACA57-FF14-4608-AE43-2C3480089B9AQ42176919-F63CCFCA-0EB7-4803-8FC5-51A990DFE142Q42255464-0E0E1469-2CDB-4758-9C0F-033050A95FF6Q42407257-D627C941-3C05-4259-AB94-B77A83FCDD71Q42431190-7BD47197-F762-4DDD-8FBE-56B736969878Q42540018-22163D11-CFD7-4687-BE90-229D8167DC02Q42591850-71C6AA41-885C-4036-8B5E-47769EFB9B3EQ42734148-5EE4FDEB-1726-4CF7-A08F-78F47712C1C0Q43119768-A9119BD8-6A50-4D2A-AADD-896344739A63Q46352544-84223909-E002-41AC-8BF6-41E39377236AQ47255682-BCBB4EEB-60E5-4121-BB12-52840F9092BDQ48259430-DD6C2378-90B6-44ED-81FD-D3D5878FBDC7Q48261568-83461907-2A28-4587-85F7-34B8CD96DA08Q50972456-A72866C5-1A54-4635-99E5-72202FEF7367Q52453693-5BCA1EAF-36B7-42DC-B63A-CF342224DB5AQ53616569-8ABD4781-F1DD-45B0-8587-FF89CBD233BDQ54593105-681D7967-D13F-4BFB-AF2B-19008F18F56D
P2860
Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Direct generation of acyclic p ...... on in polyketide construction.
@en
Direct generation of acyclic p ...... on in polyketide construction.
@nl
type
label
Direct generation of acyclic p ...... on in polyketide construction.
@en
Direct generation of acyclic p ...... on in polyketide construction.
@nl
prefLabel
Direct generation of acyclic p ...... on in polyketide construction.
@en
Direct generation of acyclic p ...... on in polyketide construction.
@nl
P2860
P356
P1476
Direct generation of acyclic p ...... on in polyketide construction.
@en
P2093
P2860
P304
12795-12800
P356
10.1021/JA204570W
P407
P577
2011-07-25T00:00:00Z