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Do (pentaarylcyclopentadienyl)molybdenum(VI) dioxo species catalyse alkene epoxidations? Insights from kinetics data.'One-pot' Hammett plots: a general method for the rapid acquisition of relative rate data.Simulations of ionic liquids, solutions, and surfaces.NMR spectroscopy to follow reaction progress in ionic liquids.Targeted and Systematic Approach to the Study of pKa Values of Imidazolium Salts in Dimethyl Sulfoxide.Incrementally increasing the length of a peptide backbone: effect on macrocyclisation efficiency.Electronic effects on the substitution reactions of benzhydrols and fluorenyl alcohols. Determination of mechanism and effects of antiaromaticity.The effects of ionic liquids on azide-alkyne cycloaddition reactions.Ionic liquids through the looking glass: theory mirrors experiment and provides further insight into aromatic substitution processes.Does the cation really matter? The effect of modifying an ionic liquid cation on an SN2 process.Ionic liquids: just Molten salts after all?Comparing the reactivity of alkynes and alkenes on silicon (100) surfaces.(79)Br NMR spectroscopy as a practical tool for kinetic analysis.Probing the importance of ionic liquid structure: a general ionic liquid effect on an S(N)Ar process.Silicon (100) electrodes resistant to oxidation in aqueous solutions: an unexpected benefit of surface acetylene moieties.NMR Diffusion Measurements as a Simple Method to Examine Solvent-Solvent and Solvent-Solute Interactions in Mixtures of the Ionic Liquid [Bmim][N(SO2 CF3 )2 ] and Acetonitrile.Putting corannulene in its place. Reactivity studies comparing corannulene with other aromatic hydrocarbons.Ionic liquid effects on a multistep process. Increased product formation due to enhancement of all steps.The central atom size effect on the structure of Group 14 tetratolyls.Central-atom size effects on the methyl torsions of Group XIV tetratolyls.Cleavage of ethers in an ionic liquid. Enhancement, selectivity and potential application.Tropylium-Promoted Oxidative Functionalization of Tetrahydroisoquinolines.Understanding the Effect of Solvent Structure on Organic Reaction Outcomes When Using Ionic Liquid/Acetonitrile Mixtures.Phase behaviour and thermodynamics: general discussion.Photochromic switching behaviour of donor-acceptor Stenhouse adducts in organic solvents.Rational selection of the cation of an ionic liquid to control the reaction outcome of a substitution reaction.Using supramolecular binding motifs to provide precise control over the ratio and distribution of species in multiple component films grafted on surfaces: demonstration using electrochemical assembly from aryl diazonium salts.The effect of varying the anion of an ionic liquid on the solvent effects on a nucleophilic aromatic substitution reaction.Rationalising the effects of ionic liquids on a nucleophilic aromatic substitution reaction.Ion - reagent interactions contributing to ionic liquid solvent effects on a condensation reactionNucleophilic Cleavage of Lignin Model Compounds under Acidic Conditions in an Ionic Liquid: A Mechanistic StudyKamlet–Taft solvent parameters, NMR spectroscopic analysis and thermoelectrochemistry of lithium–glyme solvate ionic liquids and their dilute solutionsStructure–function relationships of donor–acceptor Stenhouse adduct photochromic switchesInvestigating Solvent Effects of an Ionic Liquid on Pericyclic Reactions through Kinetic Analyses of Simple RearrangementsNovel Chloroimidazolium-Based Ionic Liquids: Synthesis, Characterisation and Behaviour as Solvents to Control Reaction OutcomeN-Heterocyclic olefins as efficient phase-transfer catalysts for base-promoted alkylation reactionsDeveloping principles for predicting ionic liquid effects on reaction outcome. The importance of the anion in controlling microscopic interactionsDeveloping principles for predicting ionic liquid effects on reaction outcome. A demonstration using a simple condensation reactionA novel route to copper(ii) detection using ‘click’ chemistry-induced aggregation of gold nanoparticlesInvestigating the origin of entropy-derived rate accelerations in ionic liquids
P50
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P50
description
hulumtues
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onderzoeker
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researcher
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հետազոտող
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name
Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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type
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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Jason B. Harper
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P106
P1153
7402361455
P21
P2798
P31
P496
0000-0003-2722-8534