Arrested 1,2-hydrogen migration from silicon to nickel upon oxidation of a three-coordinate Ni(I) silyl complex.
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Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6- (i) Pr2-C6H3)]2}Carbon-hydrogen bond activation, C-N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand.Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.Complexes of Ni(i): a "rare" oxidation state of growing importance.Nickel hydrides supported by a non-innocent diphosphine arene pincer: mechanistic studies of nickel-arene H-migration and partial arene hydrogenation.Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity.Synthesis and chemistry of bis(triisopropylphosphine) nickel(I) and nickel(0) precursors.Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H σ-complexes.Unusual structure, fluxionality, and reaction mechanism of carbonyl hydrosilylation by silyl hydride complex [(ArN=)Mo(H)(SiH2Ph)(PMe3)3].Nickel(I) monomers and dimers with cyclopentadienyl and indenyl ligands.Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes.Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C-H) Agostic Complex.Arrested α-hydride migration activates a phosphido ligand for C-H insertion.Activation of Si-H bonds across the nickel carbene bond in electron rich nickel PC(carbene)P pincer complexes.
P2860
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P2860
Arrested 1,2-hydrogen migration from silicon to nickel upon oxidation of a three-coordinate Ni(I) silyl complex.
description
2010 nî lūn-bûn
@nan
2010年の論文
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2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
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2010年论文
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name
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@en
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@nl
type
label
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@en
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@nl
prefLabel
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@en
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@nl
P2093
P356
P1476
Arrested 1,2-hydrogen migratio ...... oordinate Ni(I) silyl complex.
@en
P2093
Gregory L Hillhouse
Vlad M Iluc
P304
11890-11892
P356
10.1021/JA1052329
P407
P577
2010-09-01T00:00:00Z