Organocatalysis in cross-coupling: DMEDA-catalyzed direct C-H arylation of unactivated benzene.
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Ascorbic Acid as an Initiator for the Direct CH Arylation of (Hetero)arenes with Anilines Nitrosated In SituGeneral method for functionalized polyaryl synthesis via aryne intermediates.Base-mediated intermolecular sp2 C-H bond arylation via benzyne intermediates.Organocatalytic C-H activation reactions.A radical process towards the development of transition-metal-free aromatic carbon-carbon bond-forming reactions.To be or not to be metal-free: trends and advances in coupling chemistries.The electron is a catalyst.Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization.Transition-Metal-Free C3 Arylation of Indoles with Aryl Halides.Functionalization of C-H Bonds by Photoredox Catalysis.Mechanistic Study of a Photocatalyzed C-S Bond Formation Involving Alkyl/Aryl Thiosulfate.Mechanistic insights into the potassium tert-butoxide-mediated synthesis of N-heterobiaryls.Nickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides.Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species.Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution.Transition-metal-free alkynylation of aryl chlorides.A cascade coupling strategy for one-pot total synthesis of β-carboline and isoquinoline-containing natural products and derivatives.Direct use of formamides as amino group sources via C-N bond cleavage: a catalytic oxidative synthesis of α-ketoamides from acetophenones and formamides under metal-free conditions.Trifluoromethanesulfonic acid catalyzed synergetic oxidative/[3+2] cyclization of quinones with olefins.Synthesis of benzimidazoles by potassium tert-butoxide-promoted intermolecular cyclization reaction of 2-iodoanilines with nitriles.Toluene derivatives as simple coupling precursors for cascade palladium-catalyzed oxidative C-H bond acylation of acetanilides.Tethering for selective synthesis of 2,2'-biphenols: the acetal method.A new face of phenalenyl-based radicals in the transition metal-free C-H arylation of heteroarenes at room temperature: trapping the radical initiator via C-C σ-bond formation.Sensitization-Initiated Electron Transfer for Photoredox Catalysis.Effect of solvent on radical cyclisation pathways: SRN1 vs. aryl-aryl bond forming mechanisms.Nickel-Mediated Synthesis of Isoindolinones at Room Temperature.Direct arylation of inactivated benzene with aryl acyl peroxides toward biaryls.Direct Nucleophilic Substitution Reaction of Cage B-H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes.Tertiary amine self-catalyzed intramolecular Csp3-H functionalization with in situ generated allenes for the formation of 3-alkenyl indolines.Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n -o-Carboranes (n=1,2) and o-Carborane-Fused Cyclics.Transition-Metal-Free Radical C(sp3)-C(sp2) and C(sp3)-C(sp3) Coupling Enabled by 2-Azaallyls as Super-Electron-Donors and Coupling-Partners.Chromoselective Photocatalysis: Controlled Bond Activation through Light-Color Regulation of Redox Potentials.Transition-metal-free Chemoselective Oxidative C-C Coupling of the sp3 C-H Bond of Oxindoles with Arenes and Addition to Alkene: Synthesis of 3-Aryl Oxindoles, and Benzofuro- and Indoloindoles.N-Methylanilines as Simple and Efficient Promoters for Radical-Type Cross-Coupling Reactions of Aryl Iodides.Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles.Hydroxyl directed C-arylation: synthesis of 3-hydroxyflavones and 2-phenyl-3-hydroxy pyran-4-ones under transition-metal free conditions.Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions.Metal-Free, room-temperature, radical alkoxycarbonylation of aryldiazonium salts through visible-light photoredox catalysis.Visible Light-Induced Carbonylation Reactions with Organic Dyes as the Photosensitizers.Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed C¢X Bond Cleavage to Environmentally Benign Transition-Metal-Free C¢H Bond Activation.
P2860
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P2860
Organocatalysis in cross-coupling: DMEDA-catalyzed direct C-H arylation of unactivated benzene.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@en
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@nl
type
label
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@en
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@nl
prefLabel
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@en
Organocatalysis in cross-coupl ...... lation of unactivated benzene.
@nl
P2093
P50
P356
P1476
Organocatalysis in cross-coupl ...... ylation of unactivated benzene
@en
P2093
P304
16737-16740
P356
10.1021/JA103050X
P407
P577
2010-08-02T00:00:00Z