From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.
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Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.An Isolable Silicon Dicarbonate Complex from Carbon Dioxide Activation with a Silylone.A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes.Synthesis of a donor-stabilized silacyclopropan-1-one.Quantifying the nature of lone pair domains.A Disilene Base Adduct with a Dative Si-Si Single Bond.Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand.An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water.Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.Lewis base stabilized oxophosphonium ions.Isolable Boron Persulfide: Activation of Elemental Sulfur with a 2-Chloro-Azaborolyl Anion.A Stable Monomeric SiO2 Complex with Donor-Acceptor Ligands.Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor.Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-.Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn).Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.C-N bond cleavage and ring expansion of N-heterocyclic carbenes using hydrosilanes.Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.A Stable Silanone with a Three-Coordinate Silicon Atom: A Century-Long Wait is OverA family of [Ni8] cages templated by μ6-peroxide from dioxygen activationDouble N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silylene
P2860
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P2860
From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
From silicon
@nl
From silicon(II)-based dioxyge ...... as stable at room temperature.
@en
type
label
From silicon
@nl
From silicon(II)-based dioxyge ...... as stable at room temperature.
@en
prefLabel
From silicon
@nl
From silicon(II)-based dioxyge ...... as stable at room temperature.
@en
P2093
P2860
P356
P1433
P1476
From silicon(II)-based dioxyge ...... as stable at room temperature.
@en
P2093
Martin Kaupp
Robert Müller
Shenglai Yao
P2860
P2888
P304
P356
10.1038/NCHEM.666
P577
2010-05-30T00:00:00Z