Effects of axial pyridine coordination on a saddle-distorted porphyrin macrocycle: stabilization of hexa-coordinated high-spin Fe(III) and air-stable low-spin iron(II) porphyrinates.

Effects of axial pyridine coordination on a saddle-distorted porphyrin macrocycle: stabilization of hexa-coordinated high-spin Fe(III) and air-stable low-spin iron(II) porphyrinates.

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http://www.wikidata.org/entity/Q43057712
Diiron(III)-μ-Fluoro Bisporphyrins: Effect of Bridging Ligand on the Metal Spin State.Synthesis and characterization of a modified "picket fence" porphyrin complex - stronger π bonding interactions between Fe(ii) and axial ligands.Protonation of an oxo-bridged diiron unit gives two different iron centers: synthesis and structure of a new class of diiron(III)-μ-hydroxo bisporphyrins and the control of spin states by using counterions.Hydroxo-bridged diiron(iii) and dimanganese(iii) bisporphyrins: modulation of metal spins by counter anions.Remarkable Anion-Dependent Spin-State Switching in Diiron(III) μ-Hydroxo Bisporphyrins: What Role do Counterions Play?Effect of Inter-Porphyrin Distance on Spin-State in Diiron(III) μ-Hydroxo Bisporphyrins.Spontaneous reduction of mononuclear high-spin iron(III) complexes to mononuclear low-spin iron(II) complexes in aqueous media and nuclease activity via self-activation.Oxidation triggers extensive conjugation and unusual stabilization of two di-heme dication diradical intermediates: role of bridging group for electronic communication.
P2860

Effects of axial pyridine coordination on a saddle-distorted porphyrin macrocycle: stabilization of hexa-coordinated high-spin Fe(III) and air-stable low-spin iron(II) porphyrinates.

Item
http://www.wikidata.org/entity/Q43057712
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Effects of axial pyridine coor ...... hexa-coordinated high-spin Fe
@nl
Effects of axial pyridine coor ...... w-spin iron(II) porphyrinates.
@en
type
label
Effects of axial pyridine coor ...... hexa-coordinated high-spin Fe
@nl
Effects of axial pyridine coor ...... w-spin iron(II) porphyrinates.
@en
prefLabel
Effects of axial pyridine coor ...... hexa-coordinated high-spin Fe
@nl
Effects of axial pyridine coor ...... w-spin iron(II) porphyrinates.
@en
P1433
P1476
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698
P356
P1433
P1476
Effects of axial pyridine coor ...... ow-spin iron(II) porphyrinates
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698