Intramolecular carbolithiation of N-allyl-ynamides: an efficient entry to 1,4-dihydropyridines and pyridines - application to a formal synthesis of sarizotan.
about
Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung.SYNTHESIS OF DE NOVO CHIRAL γ-AMINO-YNAMIDES USING LITHIATED YNAMIDES. OBSERVATION OF A UNIQUE 5-ENDO-DIG CYCLIZATION WITH AN INVERSION OF S-CENTER.Regio- and stereoselective carbometallation reactions of N-alkynylamides and sulfonamides.A highly stereoselective addition of lithiated ynamides to Ellman-Davis chiral N-tert-butanesulfinyl imines.Ynamides in ring forming transformations.A Convenient Synthesis of γ-Amino-Ynamides via Additions of Lithiated Ynamides to Aryl Imines. Observation of an Aza-Meyer-Schuster Rearrangement.Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence.
P2860
Q38218769-CE311F3B-C820-46AB-8D5D-4D4AD2D23B63Q39005944-E23D3172-6AAF-402E-976C-CC3A4D11AED0Q39908226-6EE79B26-CAD5-4D5D-8DDB-24F79416494FQ41790857-4878FED3-87B1-4321-891E-2CCEC635EE9AQ42003436-A1A9BECD-5CEC-44E7-B59D-FE833D00FF2CQ42096612-0C47EABA-2894-41DA-81EA-8EFCACAAD571Q42156714-0049F0B2-7467-4D84-82DF-F307593641C2
P2860
Intramolecular carbolithiation of N-allyl-ynamides: an efficient entry to 1,4-dihydropyridines and pyridines - application to a formal synthesis of sarizotan.
description
2012 nî lūn-bûn
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name
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@en
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@nl
type
label
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@en
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@nl
prefLabel
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@en
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@nl
P2093
P2860
P356
P1476
Intramolecular carbolithiation ...... formal synthesis of sarizotan.
@en
P2093
Gwilherm Evano
Mohamed B Rammah
Mohamed M Rammah
P2860
P304
P356
10.3762/BJOC.8.250
P577
2012-12-21T00:00:00Z