Ir-catalysed asymmetric allylic substitutions with cyclometalated (phosphoramidite)Ir complexes--resting states, catalytically active (pi-allyl)Ir complexes and computational exploration.

Ir-catalysed asymmetric allylic substitutions with cyclometalated (phosphoramidite)Ir complexes--resting states, catalytically active (pi-allyl)Ir complexes and computational exploration.

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http://www.wikidata.org/entity/Q43085651
Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones.Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron SubstituentsControl of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion.Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran.Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysisDiastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolatesSyntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular Diels-Alder reactions.Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles.Facile synthesis and versatile reactivity of an unusual cyclometalated rhodium(I) pincer complex.Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.Enantioselective Synthesis of Pyrrole-Based Spiro- and Polycyclic Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions.Iridium-Catalyzed Asymmetric Allylic Amination with Polar Amines: Access to Building Blocks with Lead-Like Molecular PropertiesReversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenationEvidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement
P2860

Ir-catalysed asymmetric allylic substitutions with cyclometalated (phosphoramidite)Ir complexes--resting states, catalytically active (pi-allyl)Ir complexes and computational exploration.

Item
http://www.wikidata.org/entity/Q43085651
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Ir-catalysed asymmetric allyli ...... and computational exploration.
@en
Ir-catalysed asymmetric allyli ...... and computational exploration.
@nl
type
label
Ir-catalysed asymmetric allyli ...... and computational exploration.
@en
Ir-catalysed asymmetric allyli ...... and computational exploration.
@nl
prefLabel
Ir-catalysed asymmetric allyli ...... and computational exploration.
@en
Ir-catalysed asymmetric allyli ...... and computational exploration.
@nl
P1433
P1476
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698
P356
P1433
P1476
Ir-catalysed asymmetric allyli ...... and computational exploration.
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698