An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds.
about
Bonding and structure of disilenes and related unsaturated group-14 element compounds.Group 14 inorganic hydrocarbon analogues.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.A stable singlet biradicaloid siladicarbene: (L:)2Si.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >E=E=E< (E = C, Si, Ge, Sn, and Pb).Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.Reduction of the dihalocyclopentasilanes. A quest for a homocyclic silylene.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent.Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand.Highly Bent 1,3-Digerma-2-silaallene.A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole.A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.1,3-Diazasilabicyclo[1.1.0]butane with a Long Bridging N-N Bond.An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine.Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes.On the Reactivity of the Silylene PhC(NtBu)2SiNPh2toward Organic SubstratesEin stabiles biradikaloides Singulett-Siladicarben: (L:)2SiMetal free and selective activation of one C–F bond in a bound CF3 groupA début for base stabilized monoalkylsilylenesElegant approach to spacer arranged silagermylene and bis(germylene) compounds
P2860
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P2860
An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds.
description
2010 nî lūn-bûn
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2010年の論文
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2010年学术文章
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2010年学术文章
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2010年学术文章
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name
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@en
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@nl
type
label
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@en
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@nl
prefLabel
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@en
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@nl
P356
P1476
An isolable dialkylsilylene an ...... on of heavy unsaturated bonds.
@en
P2093
Mitsuo Kira
P304
P356
10.1039/C002806A
P407
P577
2010-03-29T00:00:00Z