Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex.
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Formation of N-heterocyclic, donor-stabilized borenium ions.Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand.New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Stable singlet carbenes as mimics for transition metal centers.E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.EH3 (E = N, P, As) and H2 activation with N-heterocyclic silylene and germylene homologues.Diverse reactivity of borenium cations with >N-H compounds.Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application.A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.Reversible formation of a blue arsasilene and isolation of air-stable emissive disilenes.Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules.Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium.Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.Unusual N-H activation of 2-aminopyrimidine: supramolecular assembly into an Ag(I) metal-organic framework.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.Reactivity studies of silylene [PhC(NtBu)2](C5Me5)Si - reactions with [M(COD)Cl]2 (M = Rh(i), Ir(i)), S, Se, Te, and BH3.Germanium(iii) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activationsDouble N–H bond activation of N,N′-bis-substituted hydrazines with stable N-heterocyclic silyleneFacile Synthesis of a Rare Chlorosilylene-BH3 Adduct
P2860
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P2860
Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@en
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@nl
type
label
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@en
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@nl
prefLabel
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@en
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@nl
P356
P1476
Steering S-H and N-H bond acti ...... ts Si(II)-->Ni(CO)(3) complex.
@en
P2093
Antje Meltzer
Carsten Präsang
P304
P356
10.1021/JA910305P
P407
P577
2010-03-01T00:00:00Z